THE SYNTHESIS AND CHARACTERIZATION OF 2 NOVEL OCTANUCLEAR MIXED-METAL CLUSTERS - [CRM3O4(O2CET)8]2NA2(M=MO,W)

被引:0
|
作者
XU, L [1 ]
LIU, H [1 ]
YAN, DC [1 ]
HUANG, JS [1 ]
ZHANG, QE [1 ]
机构
[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA
关键词
D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two novel insoluble octanuclear mixed-metal clusters with a centrosymmetric [M3O4CrCrO4M3]14+ (M=Mo, W) core have been synthesized and characterized; a strong absorption near zero magnetic field in the EPR spectrum of the CrW3 cluster is unexpectedly observed.
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页码:1507 / 1510
页数:4
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