THE SYNTHESIS AND CHARACTERIZATION OF 2 NOVEL OCTANUCLEAR MIXED-METAL CLUSTERS - [CRM3O4(O2CET)8]2NA2(M=MO,W)

被引：0
|
作者：
XU, L [1 ]
LIU, H [1 ]
YAN, DC [1 ]
HUANG, JS [1 ]
ZHANG, QE [1 ]
机构：
[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 19期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel insoluble octanuclear mixed-metal clusters with a centrosymmetric [M3O4CrCrO4M3]14+ (M=Mo, W) core have been synthesized and characterized; a strong absorption near zero magnetic field in the EPR spectrum of the CrW3 cluster is unexpectedly observed.
引用
收藏
页码：1507 / 1510
页数：4
相关论文
共 50 条
  • [1] THE SYNTHESIS AND STRUCTURE OF A NOVEL OCTANUCLEAR MIXED-METAL CLUSTER [VW3O4(O(2)CET)(8)]2NA2
    LIU, H
    XU, L
    HUANG, JS
    ZHANG, QE
    ACTA CHIMICA SINICA, 1995, 53 (02) : 152 - 157
  • [2] SYNTHESIS, MECHANISM OF FORMATION AND CHARACTERIZATION OF A NEW CLASS OF OCTANUCLEAR MIXED-METAL CLUSTERS NA2M'2[M3O4(O2CET)8]2 (M'=CR OR V, M=MO OR W)
    LI, X
    HUANG, L
    YAN, DC
    HUANG, JS
    ZHANG, QN
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (14): : 2099 - 2107
  • [3] Synthesis and structural characterization of octanuclear indium-tungsten mixed-metal carboxylate cluster, Na2[W3InO4(O2CEt)8]2
    Xu, L
    Cui, Y
    Huang, JS
    CHEMISTRY LETTERS, 1998, (01) : 35 - 36
  • [4] A novel octanuclear mixed-metal cluster: Na-2[Cr0.5Fe0.5Mo3O4(O(2)CEt)(8)](2)
    Liu, H
    Xu, L
    Huang, JS
    Chen, WD
    Zhang, QE
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 69 - 72
  • [5] ［Vmo3O4（O2CEt）8］2Na2的合成与结构
    刘晃
    徐立
    黄锦顺
    张乾二
    Chinese Journal of Structural Chemistry, 1994, (03) : 170 - 176
  • [6] Synthesis, characterization and X-ray structure of one-dimensional polymeric complexes with triangular molybdenum clusters as building blocks:: Na2Ga2[Mo3O4(O2CEt)8]2 and Na2AlGa[Mo3O4(O2CEt)8]2
    Cui, Y
    Zhang, X
    Huang, JS
    POLYHEDRON, 1999, 18 (26) : 3411 - 3416
  • [7] Synthesis and crystal structures of three novel octanuclear heterometallic clusters Na2V2[Mo3O4(OAc)(8)](2)center dot H2O, Na2Cr2[Mo1.5W1.5O4(O(2)CEt)(8)](2) and Na2Al2[Mo2WO4(O(2)CEt)(8)](2)
    Xu, L
    Li, ZF
    Liu, H
    Huang, JS
    TRANSITION METAL CHEMISTRY, 1996, 21 (06) : 498 - 502
  • [8] Syntheses, crystal structures, and properties of novel heterooctametallic clusters Na2M2'[M3O4(O2CEt)(8)](2) (M'=Fe, Cr, Mo; M-3=Mo-3, MoW2, W-3)
    Xu, L
    Li, ZH
    Liu, H
    Huang, JS
    Zhang, QE
    CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (02) : 226 - 231
  • [9] Synthesis and characterization of the tungsten-gallium heterometallic cluster Na2[W3GaO4(O2CEt)8]2
    Cui, Y
    Xu, L
    Huang, JS
    INORGANICA CHIMICA ACTA, 1998, 277 (01) : 130 - 133
  • [10] Synthesis, characterization and properties of two novel octanuclear heterometallic molecules consisting of two triangular molybdenum clusters bridged by oxochromium ligands: M(2)[Mo3O4(O(2)CEt)(8)Cr-2(O(2)CEt)(8)O4Mo3]center dot n(HO(2)CEt) (M=K, n=2; M=Li, n=0)
    Liu, H
    Xu, L
    Huang, JS
    Chen, WD
    Huang, XY
    Huang, X
    POLYHEDRON, 1996, 15 (12) : 2003 - 2010
12345