DIASTEREOSELECTIVE [3+2] CYCLOADDITION OF METHYL 2-PHENLTHIOCYCLOPROPYL KETONE WITH ENOL SILYL ETHERS - SYNTHESIS OF FUNCTIONALIZED CYCLOPENTANES

被引：34
|
作者：
HORIGUCHI, Y [1 ]
SUEHIRO, I [1 ]
SASAKI, A [1 ]
KUWAJIMA, I [1 ]
机构：
[1] TOKYO INST TECHNOL, DEPT CHEM, MEGURO KU, TOKYO 152, JAPAN
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 38期
关键词：
D O I：
10.1016/S0040-4039(00)61732-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Dimethylaluminum chloride-mediated [3 + 2] cycloaddition of methyl 2-phenylthiocyclopropyl ketone and enol TBDPS or TIPS ethers proceeds highly diastereoselectively to afford functionalized cyclopentanes in good yields.
引用
收藏
页码：6077 / 6080
页数：4
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