THE BAMBERGER REACTION IN HYDROGEN-FLUORIDE - THE USE OF MILD REDUCTIVE METALS FOR THE PREPARATION OF FLUOROAROMATIC AMINES

被引：8

作者：

TORDEUX, M ^{[1
]}

WAKSELMAN, C ^{[1
]}

机构：

[1] UNIV VERSAILLES, SIRCOB, F-78000 VERSAILLES, FRANCE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 74卷 / 02期

关键词：

BAMBERGER REACTION; HYDROGEN FLUORIDE; MILD REDUCTIVE METALS; FLUOROAROMATIC AMINES; NMR SPECTROSCOPY;

D O I：

10.1016/0022-1139(95)03257-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of nitroaromatic compounds by various metals (tin, lead, bismuth) in liquid hydrogen fluoride under an inert atmosphere leads to fluoroaromatic amines, in accord with the Bamberger reaction. Generally, a co-solvent such as pentane or methylene chloride is used. Some non-fluorinated arylamines are also formed by a competitive direct reduction of the N-arylhydroxylamine intermediate. Of the mild reductive metals studied, bismuth was the most selective.

引用

页码：251 / 254

页数：4

共 50 条

[31] PREPARATION OF ANHYDROUS FEF3 BY SOLID-STATE REACTION OF IRON-OXIDE WITH AMMONIUM HYDROGEN-FLUORIDE
JUNEJA, JM
SINGH, S
ADHYAPAK, SV
RAO, URK
INDIAN JOURNAL OF ENGINEERING AND MATERIALS SCIENCES, 1995, 2 (03) : 136 - 138
[32] STUDY OF FLUORINE EVOLUTION REACTION AT A PLATINUM-ELECTRODE IN ANHYDROUS HYDROGEN-FLUORIDE
DOUGHTY, AG
FLEISCHM.M
PLETCHER, D
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 51 (02): : 329 - 339
[33] S-METHYLATION OF METHIONINE, A SIDE REACTION OF DEPROTECTION BY HYDROGEN-FLUORIDE ANISOL
BIENERT, M
KATZWINKEL, S
SCHWARZ, J
ZEITSCHRIFT FUR CHEMIE, 1983, 23 (10): : 375 - 376
[34] THEORETICAL-STUDY OF THE ADDITION OF HYDROGEN HALIDES TO OLEFINS - REACTION OF DIMERIC HYDROGEN-FLUORIDE WITH ETHYLENE
CLAVERO, C
DURAN, M
LLEDOS, A
VENTURA, ON
BERTRAN, J
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (05) : 923 - 928
[35] REACTION-RATES FOR GAS-PHASE HYDROGEN-FLUORIDE SACCHARIFICATION OF WOOD
HAWLEY, MC
RORRER, GL
LAMPORT, DTA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 190 (SEP): : 108 - MBD
[36] CHEMISTRY IN HYDROGEN-FLUORIDE .5. CATALYSTS FOR REACTION OF HF WITH HALOGENATED OLEFINS
FEIRING, AE
JOURNAL OF FLUORINE CHEMISTRY, 1979, 14 (01) : 7 - 18
[37] THE POSSIBLE FORMATION OF HYDROGEN-FLUORIDE FROM THE REACTION OF SILICON TETRAFLUORIDE WITH HUMID AIR
RICKS, GM
JOHNSON, DE
SCHAEFFER, EM
AMERICAN INDUSTRIAL HYGIENE ASSOCIATION JOURNAL, 1993, 54 (05): : 272 - 276
[38] HYDROGEN-FLUORIDE - ANISOLE CATALYZED REACTION WITH GLUTAMIC-ACID CONTAINING PEPTIDES
SANO, S
KAWANISHI, S
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (12) : 3480 - 3484
[39] REACTION-RATES FOR GAS-PHASE HYDROGEN-FLUORIDE SACCHARIFICATION OF WOOD
RORRER, GL
HAWLEY, MC
LAMPORT, DTA
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1986, 25 (04): : 589 - 595
[40] STUDY ON ELECTRODE OF USE COMPARISON IN ANHYDROUS HYDROGEN-FLUORIDE - DETERMINATION OF RELAX POTENTIAL OF FLUORINE AND HYDROGEN
MOUGIN, J
ROYON, J
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1973, 276 (10): : 819 - 822

← 1 2 3 4 5 →