LINEAR CO-POLYMERIZATION OF TRANS-[PT(C(2)BU(T))(2)(PME(2)PH)(2)] WITH COPPER(I) CHLORIDE

被引：23
|
作者：
YAMAZAKI, S
DEEMING, AJ
HURSTHOUSE, MB
MALIK, KMA
机构：
[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND
[2] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,S GLAM,WALES
来源：
INORGANICA CHIMICA ACTA | 1995年 / 235卷 / 1-2期
关键词：
CRYSTAL STRUCTURES; COPPER ALKYNE COMPLEXES; PLATINUM ALKYNYL COMPLEXES; CO-POLYMERIZATION;
D O I：
10.1016/0020-1693(95)90055-B
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of cis-[PtCl2(PMe(2)Ph)(2)] with the alkyne Bu(t)C(2)H and Et(2)NH in the presence of solid CuCl (> 0.35 mol/mol Pt) leads to the formation of colourless crystals of the compound trans-[{PtCu2Cl2(C(2)Bu(t))(2)(PMe(2)Ph)(2)}(n)]. 2n(MeCN) from acetonitrile solution for which the X-ray structure has been determined. The compound crystallises in the triclinic space group P $($) over bar$$ 1 with a = 9.505(4), b = 12.374(5), c = 15.970(2) Angstrom, alpha = 82.94(1), beta = 86.61(3), gamma = 77.98(2)degrees, V = 1822(1) Angstrom(3), Z = 2 (formula with n = 1). A linear polymeric structure is adopted which contains Pt(mu-sigma,eta(2)-C2BUt)Cu and Cu(mu-Cl)(2)Cu linkages. Several modes of alkyne-copper coordination have now been characterised with from one up to four alkyne groups coordinated to each copper atom.
引用
收藏
页码：147 / 150
页数：4
相关论文
共 50 条
  • [21] REACTIONS OF 1-ALKYNES WITH TRANS-[RECL(N2)(PH2PCH2CH2PPH2)2] - PREPARATION OF THE VINYLIDENE COMPOUNDS TRANS-[RECL(=C=CH-ALKYL)(PH2PCH2CH2PPH2)2], TRANS-[RECL(=C=CH-ARYL)(PH2PCH2CH2PPH2)2] AND X-RAY STRUCTURE OF TRANS-[RECL(=C=CHPH)-(PH2PCH2CH2PPH2)2]
    POMBEIRO, AJL
    ALMEIDA, SSPR
    SILVA, MFCG
    JEFFREY, JC
    RICHARDS, RL
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (12): : 2381 - 2387
  • [22] STRUCTURES OF [(T)BUCPFE(CO)(2)](2) AND [(T)BU(2)CPFE(CO)(2)](2)
    COTTON, JD
    BYRIEL, KA
    KENNARD, CHL
    SCHECK, T
    LYNCH, DE
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) : 243 - 246
  • [23] REACTION OF PT3(CO)3(P-TERT-BU2PH)3 AND HCL - THE X-RAY STRUCTURE OF PT2CL2(CO)2(P-TERT-BU2PH)2
    COUTURE, C
    FARRAR, DH
    FISHER, DS
    GUKATHASAN, RR
    ORGANOMETALLICS, 1987, 6 (03) : 532 - 536
  • [24] Synthesis and X-ray crystal structures of [Ph(2)PMe(2)][(eta(5)-C(5)H(4)Bu(t))(2)Li] and [(eta(5)-C(5)H(4)Bu(t))(2)Yb(Cl)CH2P(Me)Ph(2)]
    Wong, WK
    Zhang, LL
    Wong, WT
    Xue, F
    Mak, TCW
    POLYHEDRON, 1996, 15 (24) : 4593 - 4597
  • [25] PROTONATION OF TRANS-[MO(ETA(2)-MECCH)(2)(PH(2)PCH(2)CH(2)PPH(2))(2)] - MECHANISM OF FORMATION OF TRANS-[MOX(CHCHME)(PH(2)PCH(2)CH(2)PPH(2))(2)] (X=CL OR BR) OR TRANS-[MOF(CCH(2)ME)(PH(2)PCH(2)CH(2)PPH(2))(2)]
    HENDERSON, RA
    OGLIEVE, KE
    SALISBURY, P
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (15): : 2479 - 2487
  • [26] Photochemistry of cis,trans-[Pt(en)(I)2(OH)2] complex in aqueous solutions
    Glebov, Evgeni M.
    Pozdnyakov, Ivan P.
    Vasilchenko, Danila B.
    Zadesenets, Andrey V.
    Melnikov, Alexey A.
    Magin, Ilya M.
    Grivin, Vjacheslav P.
    Chekalin, Sergey V.
    Plyusnin, Victor F.
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2018, 354 : 78 - 85
  • [27] ANIONIC-POLYMERIZATION AND CO-POLYMERIZATION OF 2-METHYL-2-ETHYLTHIIRANE
    RAKOTOMANGA, A
    HEMERY, P
    BOILEAU, S
    LOTZ, B
    EUROPEAN POLYMER JOURNAL, 1978, 14 (08) : 581 - 587
  • [28] PREPARATION AND PROPERTIES OF MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES .42. PREPARATION AND CHARACTERIZATION OF W(V) DIAZOALKANE COMPLEXES MER,TRANS-[WX(3)(NN=CMER)(PME(2)PH)(2)](X=BR,IR=ME,PH) AND HYDRAZIDO(2-) COMPLEX [WT,(NNH2)(PME(2)PH)(2)] - X-RAY STRUCTURE OF MER,TRANS-[WBR3(NN=CMEPH)(PME(2)PH)(2)]
    OSHITA, H
    MIZOBE, Y
    HIDAI, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 461 (1-2) : 43 - 49
  • [29] METALLACUMULENES - ACTIVATION OF DIYNES AND FORMATION OF NEW ALLENYLIDENERUTHENIUM COMPLEXES - CRYSTAL-STRUCTURES OF TRANS-[(PH(2)PCH(2)PPH(2))(2)(CL)RU=C=C=CR(1)R(2)](+) AND TRANS-[(PH(2)PCH(2)PPH(2))(2)RU(=C=C=C(OME)CH=CPH(2))(2)](2+)
    TOUCHARD, D
    PIRIO, N
    TOUPET, L
    FETTOUHI, M
    OUAHAB, L
    DIXNEUF, PH
    ORGANOMETALLICS, 1995, 14 (11) : 5263 - 5272
  • [30] PREPARATION OF TRANS-[PT(N3)4BR2]2-,TRANS-[PT(N3)-4I2]2-,TRANS-[PT(N3)4SCN2]2-,TRANS-[PT(N3)4SECN2]2- BY OXIDATIVE ADDITION TO [PT(N3)4]2- IN ORGANIC-SOLVENTS
    PREETZ, W
    GRABOWSKI, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 518 (11): : 129 - 136
12345