KINETICS OF THE INITIAL STEP OF CATALYTIC RADICAL-CHAIN OXIDATION OF CUMENE, INCLUDING CATALYST DEACTIVATION STEP

被引：0
|
作者：
OPEIDA, IA [1 ]
ZALEVSKAYA, NM [1 ]
VASILIEV, AY [1 ]
机构：
[1] LM LITVINENKO INST PHYSICOORGAN CHEM & COAL CHEM,DONETSK,UKRAINE
来源：
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1994年 / 30卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A method has been developed for estimating the reaction rate constants of deactivation of an autocatalytic free radical-chain process catalyst in the presence of low-stability catalysts. Its applicability has been exemplified by tetralkylammonium halide-catalyzed cumene oxidation.
引用
收藏
页码：69 / 74
页数：6
相关论文
共 39 条
  • [11] Use of heterogeneous activated carbon supported copper catalyst for catalytic wet oxidation of biomethanated spent wash: Reaction kinetics, catalyst stability, catalyst deactivation kinetics and biochemical methane potential
    Khatri, Inderjeet
    Garg, Anurag
    JOURNAL OF WATER PROCESS ENGINEERING, 2021, 44
  • [12] EVALUATION OF THE ROLE OF THE PROTON RETURN STEP IN THE KINETICS OF THE ISOTOPIC EXCHANGE OF HYDROGEN IN CUMENE IN A DIMSYL POTASSIUM DIMETHYL-SULFOXIDE CATALYTIC-SYSTEM
    SHAPIRO, IO
    RANNEVA, YI
    SHATENSHTEIN, AI
    KINETICS AND CATALYSIS, 1984, 25 (05) : 1067 - 1071
  • [13] Kinetics and Mechanism of Radical-Chain Oxidation of 1,2-Substituted Ethylene and 1,4-Substituted Butadiene-1,3
    Pliss, E. M.
    Machtin, V. A.
    Grobov, A. M.
    Pliss, R. E.
    Sirick, A. V.
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2017, 49 (03) : 173 - 181
  • [14] Ceria promoted γ-Al2O3 supported platinum catalyst for catalytic wet air oxidation of oxalic acid: kinetics and catalyst deactivation
    Roy, Shyamal
    Saroha, Anil Kumar
    RSC ADVANCES, 2014, 4 (100) : 56838 - 56847
  • [15] Catalytic performance and deactivation mechanism of a one-step sulfonated carbon-based solid-acid catalyst in an esterification reaction
    Zhang, Bingxin
    Gao, Ming
    Geng, Jiayu
    Cheng, Yuwei
    Wang, Xiaona
    Wu, Chuanfu
    Wang, Qunhui
    Liu, Shu
    Cheung, Siu Ming
    RENEWABLE ENERGY, 2021, 164 : 824 - 832
  • [16] SIMULATION OF POLYCHROMATIC KINETICS OF THE PROPAGATION STEP OF THE CHAIN OXIDATION REACTION IN STRAINED POLYPROPYLENE BASED ON THE ROTATIONAL ISOMERS MODEL
    RAPOPORT, NY
    MOSTOVAYA, YM
    ZAIKOV, GY
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1986, 28 (08): : 1620 - 1628
  • [17] Kinetics of the radical-chain oxidation of methyl oleate inhibited by 5-amino-6-methyluracil and 5-amino-1,3,6-trimethyluracil
    Sakhautdinova, R. A.
    Gimadieva, A. R.
    Yakupova, L. R.
    Borisov, I. M.
    Safiullin, R. L.
    KINETICS AND CATALYSIS, 2015, 56 (02) : 125 - 131
  • [18] Kinetics of the radical-chain oxidation of methyl oleate inhibited by 5-amino-6-methyluracil and 5-amino-1,3,6-trimethyluracil
    R. A. Sakhautdinova
    A. R. Gimadieva
    L. R. Yakupova
    I. M. Borisov
    R. L. Safiullin
    Kinetics and Catalysis, 2015, 56 : 125 - 131
  • [19] Enhanced catalytic performance of a PdO catalyst prepared via a two-step method of in situ reduction-oxidation
    Hu, Wei
    Li, Guang-Xia
    Chen, Jian-Jun
    Huang, Fu-Jin
    Wu, Yang
    Yuan, Shan-Dong
    Zhong, Lin
    Chen, Yao-Qiang
    CHEMICAL COMMUNICATIONS, 2017, 53 (45) : 6160 - 6163
  • [20] Monte Carlo and cellular automata modeling of CO oxidation on a catalytic surface including the Eley-Rideal step and CO diffusion
    Sreekumar, P
    Jayaraman, VK
    Kulkarni, BD
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (06) : 2188 - 2192
1234