KINETICS OF THE INITIAL STEP OF CATALYTIC RADICAL-CHAIN OXIDATION OF CUMENE, INCLUDING CATALYST DEACTIVATION STEP

被引：0

作者：

OPEIDA, IA ^{[1
]}

ZALEVSKAYA, NM ^{[1
]}

VASILIEV, AY ^{[1
]}

机构：

[1] LM LITVINENKO INST PHYSICOORGAN CHEM & COAL CHEM,DONETSK,UKRAINE

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1994年 / 30卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method has been developed for estimating the reaction rate constants of deactivation of an autocatalytic free radical-chain process catalyst in the presence of low-stability catalysts. Its applicability has been exemplified by tetralkylammonium halide-catalyzed cumene oxidation.

引用

页码：69 / 74

页数：6

共 39 条

[1] Effect of the Polarity of the Medium on the Kinetics of the Radical-Chain Oxidation of Cumene in the Presence of Ascorbic Acid
I. V. Efimova
O. V. Smirnova
I. A. Opeida
Russian Journal of Physical Chemistry A, 2019, 93 : 661 - 664
[2] Effect of the Polarity of the Medium on the Kinetics of the Radical-Chain Oxidation of Cumene in the Presence of Ascorbic Acid
Efimova, I. V.
Smirnova, O. V.
Opeida, I. A.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 93 (04) : 661 - 664
[3] Initiation of Radical-Chain Aerobic Oxidation of Cumene by Potassium Permanganate and N-Hydroxysuccinimide
L. I. Opeida
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O. Y. Havunko
L. K. Volkova
Theoretical and Experimental Chemistry, 2024, 60 (2) : 133 - 140
[4] Catalytic oxidation of aqueous phenolic solutions catalyst deactivation and kinetics
Hamoudi, S
Belkacemi, K
Larachi, F
CHEMICAL ENGINEERING SCIENCE, 1999, 54 (15-16) : 3569 - 3576
[5] Step-growth irreversible deactivation radical polymerization: synergistic developments with chain-growth reversible deactivation radical polymerization
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2024, 97 (07)
[6] Kinetics of radical chain cumene oxidation initiated by α-oxycyclohexylperoxides in the presence of Et4NBr
Turovskiy, M. A.
Opeida, I. O.
Turovskaya, O. M.
Raksha, O. V.
Kuznetsova, N. O.
Zaikov, G. E.
OXIDATION COMMUNICATIONS, 2006, 29 (02): : 249 - 257
[7] KINETICS OF INITIAL STEP IN A BRANCHED-CHAIN REACTION UNDER FLOW CONDITIONS
GERSHENZON, YM
KINETICS AND CATALYSIS, 1976, 17 (05) : 979 - 985
[8] REACTION-KINETICS OF CATALYTIC METHANE OXIDATION AND DEACTIVATION OF A PALLADIUM CATALYST BY HYDROGEN-SULFIDE DURING CATALYTIC-OXIDATION OF METHANE
KLOSE, W
FEUERRIEGEL, U
CHEMIE INGENIEUR TECHNIK, 1993, 65 (10) : 1242 - 1243
[9] KINETICS, MASS-TRANSFER, AND PALLADIUM CATALYST DEACTIVATION IN THE HYDROGENATION STEP OF THE HYDROGEN-PEROXIDE SYNTHESIS VIA ANTHRAQUINONE
SANTACESARIA, E
DISERIO, M
VELOTTI, R
LEONE, U
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (02) : 277 - 284
[10] Modeling the Catalyst Activation Step in a Metal-Ligand Radical Mechanism Based Water Oxidation System
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Meijer, Evert Jan
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