NEW SYNTHETIC ROUTES TO CATIONIC ARENE PI-COMPLEXES OF TRANSITION-METALS

被引：1

作者：

RYBINSKAYA, MI

KAGANOVICH, VS

机构：

[1] A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 07期

关键词：

ARENE PI-COMPLEXES; ORGANOMETALLIC CATIONS; METALLOCYCLOPHANES; BINUCLEAR COMPLEXES;

D O I：

10.1007/BF00701989

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review is given of the authors' studies on the development of new methods for the synthesis of cationic arene complexes of transition metals. The synthesis in strong protic acids facilitated obtaining pi-arene cations of Mn, Re, Ru, Os, Co, Rh and Ir. New nonacidic methods allowed the set of available cationic arene pi-complexes of Mn, Ru, Rh and pi to be increased considerably. Based on the developed methods a number of previously unknown binuclear organometallic cations are obtained.

引用

页码：1128 / 1136

页数：9

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