CONTROLLING THE NUMBER OF BRIDGING LIGANDS IN BINUCLEAR IRON THIOLATE COMPLEXES BY MODULATION OF LIGAND NUCLEOPHILICITIES - [FE2(SC4H9)5]-, THE 1ST COMPLEX CONTAINING FES4 TETRAHEDRA CONNECTED VIA COMMON FACES, AND [FE2(SC3H7)6]2-, A COMPLEX WITH A BITETRAHEDRAL M2S6 FRAMEWORK OF CONVENTIONAL DESIGN

被引：25

作者：

HENKEL, G ^{[1
]}

CHEN, CN ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST STRUCT MATTER,FUZHOU,PEOPLES R CHINA

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1021/ic00059a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Fe2(SC4H9)5]-, the first compound containing FeS4 tetrahedra which share common faces, has been synthesized by reaction of FeCl2 with sodium 2-methyl-2-propanethiolate and characterized by X-ray diffraction methods. The sulfur framework of this novel iron thiolate complex is a trigonal bipyramid which surrounds two iron atoms 2.634 angstrom apart from each other. The use of 2-propanethiolate ligands results in the formation of [Fe2(SC3H7)6]2-, a binuclear complex with two bridging thiolate ligands.

引用

页码：1064 / 1065

页数：2

共 10 条

[1] [NI-2(SC4H9)(6)](2-), A NOVEL BINUCLEAR NICKEL-THIOLATE COMPLEX WITH NIS4 TETRAHEDRA SHARING EDGES AND [NI(SC(6)H(4)SIME(3))(4)](2-), A STRUCTURALLY RELATED MONONUCLEAR COMPLEX ION
MULLER, A
HENKEL, G
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (10): : 1464 - 1468
[2] Iron carbonyls with bulky thiolate ligands:: crystal structures of [Fe2(CO)6(μ-SC6H2iPr3-2,4,6)2] and (C6H2iPr3-2,4,6)2S2
Delgado, E
Hernández, E
Mansilla, N
Zamora, F
Martínez-Cruz, LA
[J]. INORGANICA CHIMICA ACTA, 1999, 284 (01) : 14 - 19
[3] PENTACOORDINATED IRON-SULFUR COMPLEXES I.SYNTHESIS AND STRUCTURE OF DINUCLEAR COMPLEX [Fe2（o-SC6H4S-S,S'）4]（Et4N）2
Wong Linhong Kang BeishengFujian Institute of Research on the Structure of Matter
[J]. Chinese Journal of Structural Chemistry, 1987, (02) : 94 - 97
[4] Experimental and theoretical studies of the structure and IR spectra of neutral diamagnetic binuclear iron nitrosyl complexes Fe2(μ-SC6-n H5-nNn)2(NO)4 (n=0, 1, 2)
Shestakov, A. F.
Shul'ga, Yu. M.
Emel'yanova, N. S.
Sanina, N. A.
Aldoshin, S. M.
[J]. RUSSIAN CHEMICAL BULLETIN, 2006, 55 (12) : 2133 - 2142
[5] ACTION OF AN ALKYLTHIOALKYNE ON IRON CARBONYL - SYNTHESES AND STRUCTURAL STUDIES OF THE 3 CLUSTERS [FE4 (CO)12 (MU-SC2H5) (MU-4, ETA-CCCH3)], [FE2 (CO)6 (MU-SC2H5) (MU-C (SC2H5) C [C (CH3) CCCH3])] AND [FE4 (CO)12 (MU-4-S) (MU-SC2H5)2] INVOLVING 3 DIFFERENT BEHAVIORS OF THE LIGAND
JEANNIN, S
JEANNIN, Y
ROBERT, F
ROSENBERGER, C
[J]. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1992, 314 (11): : 1165 - 1170
[6] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND ELECTRONIC-STRUCTURES OF THE MIXED TERMINAL LIGAND CUBANES [FE4S4CL2(XC6H5)2]2- (X = S, O) AND [FE4S4(SC6H5)2(OC6H4-P-CH3)2]2- - THE 1ST EXAMPLES OF [FE4S4]2+ CORES WITH A NONCOMPRESSED D2D IDEALIZED GEOMETR
KANATZIDIS, MG
BAENZIGER, NC
COUCOUVANIS, D
SIMOPOULOS, A
KOSTIKAS, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (16) : 4500 - 4511
[7] Reactivity of C6F5S-P(C6H5)2 with [M3(CO)12] (M = Fe, Ru, Os).: The X-ray crystal structures of [Fe2(μ-SC6F5)(μ-PPh2)(CO)6], [Ru4(μ3-SPPh2)2(μ-SC6F5)2(μ-PPh2)2(SC6F5)2(CO)6] and [Os3(η1-Ph2P-SC6F5)(CO)11]
Baldovino-Pantaleón, O
Ríos-Moreno, G
Toscano, RA
Morales-Morales, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (12) : 2880 - 2887
[8] STRUCTURAL CHARACTERIZATION OF THE IRON-BRIDGED DOUBLE-CUBANE CLUSTER COMPLEXES [MO2FE7S8(SC2H5)12]3- AND [M2FE7S8(SCH2C6H5)12]4- (M=MO,W) CONTAINING MFE3S4 CORES
WOLFF, TE
BERG, JM
POWER, PP
HODGSON, KO
HOLM, RH
[J]. INORGANIC CHEMISTRY, 1980, 19 (02) : 430 - 437
[9] SYNTHETIC ANALOGS OF ACTIVE-SITES OF IRON-SULFUR PROTEINS .7. LIGAND SUBSTITUTION-REACTION OF TETRANUCLEAR CLUSTERS [FE4S4(SR)4]2- AND STRUCTURE OF [(CH3)4N]2[FE4S4(SC6H5)4]
QUE, L
BOBRIK, MA
IBERS, JA
HOLM, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (13) : 4168 - 4178
[10] Transformation of the C2H ligand in Fp*C=CH (Fp* = (η5-C5Me5)Fe(CO)2) into various C2 functional groups via an iron-substituted manganese vinylidene complex, (η5-C5H4Me)Mn(CO)2[=C=C(H)Fp*]. Its amphoteric reactivities, structural comparisons relevant to 1-alkyne-to-vinylidene rearrangements, and electronic influences on structures of heterobimetallic bridging alkynyl complexes [(η5-C5R6)M(CO)2]2 (μ-C2R)
Akita, M.
Ishii, N.
Takabuchi, A.
Tanaka, M.
Moro-oka, Y.
[J]. Organometallics, 1994, 13 (01)

← 1 →