Transformation of the C2H ligand in FpC=CH (Fp = (η5-C5Me5)Fe(CO)2) into various C2 functional groups via an iron-substituted manganese vinylidene complex, (η5-C5H4Me)Mn(CO)2[=C=C(H)Fp*]. Its amphoteric reactivities, structural comparisons relevant to 1-alkyne-to-vinylidene rearrangements, and electronic influences on structures of heterobimetallic bridging alkynyl complexes [(η5-C5R6)M(CO)2]2 (μ-C2R)

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Akita, M.

Ishii, N.

Takabuchi, A.

Tanaka, M.

Moro-oka, Y.

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Organometallics | 1994年 / 13卷 / 01期

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[8] Synthesis and characterization of complexes η5,η5-(CO)3Mn(C5H4-C5H4)(CO)2Fe-η1,η5-C5H4Mn(CO)3 and μ-(C≡C)[C5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3]2
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