POLY(N-VINYLHALOGENOCARBAZOLE) .2. SYNTHESIS OF SOME 1,3,6,8-TETRAHALOGENO-VINYLCARBAZOLES

被引：13

作者：

PIELICHOWSKI, J

KYZIOL, JB

机构：

[1] CRACOW POLYTECH INST,ORG CHEM & TECHNOL DEPT,CRACOW,POLAND

[2] OPOLE GRAD PEDAG SCH,CHEM INST,OPOLE,POLAND

来源：

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS | 1976年 / 14卷 / 03期

关键词：

CHLORINE COMPOUNDS - Polymerization - POLYMERS - Chemistry;

D O I：

10.1002/pol.1976.130140308

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper presents results of a research program in which several vinyl carbazole polymers containing chlorine and bromine atoms in their molecules were polymerized and characterized by IR spectroscopy and thermoanalysis. The compounds were synthesized by reacting 2-chloroethanol benzenesulfonate with the appropriate halogenocarbazoles (Clemo-Perkin method) obtaining in this way some halogen derivatives of 9-(2-chloroethyl)carbazole; these derivatives following dehydrochlorination produced relevant vinyl derivatives. Results are evaluated in terms of reaction mechanisms and molecular structures of polymers synthesized.

引用

页码：153 / 159

页数：7

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