4-COORDINATE COPPER(I) IODIDE COMPLEXES WITH TRIPHENYLPHOSPHINE AND HETEROCYCLIC THIONE LIGANDS - THE CRYSTAL-STRUCTURE OF [CU(PPH3)2(PYMTH)I]

被引：50
|
作者：
ASLANIDIS, P [1 ]
HADJIKAKOU, SK [1 ]
KARAGIANNIDIS, P [1 ]
GDANIEC, M [1 ]
KOSTURKIEWICZ, Z [1 ]
机构：
[1] ADAM MICKIEWICZ UNIV POZNAN,DEPT CRYSTALLOG,PL-61712 POZNAN,POLAND
来源：
POLYHEDRON | 1993年 / 12卷 / 18期
关键词：
D O I：
10.1016/S0277-5387(00)88260-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Cu(PPh3)I]4 reacts with heterocyclic thiones (L) [L = pyrimidine-2-thione (pymtH), 1,3-thiazoline-2-thione (tzdtH), 1,3-imidazoline-2-thione (imtH), benz-1,3-imidazoline-2-thione (bzimtH-2) and benz-1,3-thiazoline-2-thione (bztztH)] in the presence of triphenylphosphine to give mononuclear complexes of the general formula [Cu(PPh3)2 (L)I]. These complexes have been characterized by various physicochemical methods. The crystal structure of [Cu(PPh3)2(pymtH)I] has been determined by single-crystal X-ray diffraction methods. The molecule is mononuclear, with a distorted tetrahedral geometry and bond lengths Cu-S = 2.338(4), Cu-I = 2.674(2), Cu-P = 2.296(4) and 2.303(4) angstrom.
引用
收藏
页码：2221 / 2226
页数：6
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