AN ABINITIO MOLECULAR-ORBITAL STUDY OF THE INSERTIONS OF DIFLUOROCARBENE OR FLUOROCARBENE INTO ETHENE

被引：0

作者：

WONG, CK ^{[1
]}

CHEUNG, CY ^{[1
]}

MA, NL ^{[1
]}

LI, WK ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG, DEPT CHEM, SHA TIN, HONG KONG

来源：

JOURNAL OF CHEMICAL RESEARCH | 1993年 / 01期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inclusion of correlation effects in ab initio MO calculations yields an activation energy for the insertion of difluorocarbene into ethene that is in excellent agreement with the experimental result; a similar calculation predicts that the insertion of fluorocarbene into ethene requires no activation energy.

引用

页码：32 / 33

页数：2

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