A CONVENIENT ELECTROSYNTHESIS OF NEW COMPLEXES [SN(CO(CO)(3)PR(3))(4)] AND THEIR SPECTROSCOPIC CHARACTERIZATION

被引：0
|
作者：
RIETHER, KB
PELLEGRINI, S
MORTREUX, A
MONFLIER, E
机构：
[1] UNIV SCI & TECH LILLE FLANDRES ARTOIS,ECOLE NATL SUPER CHIM LILLE,CHIM ORGAN APPL LAB,CNRS,F-59652 VILLENEUVE DASCQ,FRANCE
[2] UNIV ARTOIS,FAC SCI J PERRIN,F-62307 LENS,FRANCE
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 486卷 / 1-2期
关键词：
TIN; COBALT; PHOSPHINE; WATER-SOLUBLE PHOSPHINES; PHOSPHINE COMPLEXES; ELECTROCHEMISTRY;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New complexes [Sn{Co(CO)(3)PR(3)}], which have been identified by FTIR, mass spectroscopy, P-31{H-1} and Sn-119{H-1} NMR, were obtained easily in high yield (70-80%) by electroreduction of a series of water-soluble or water-insoluble complexes [Co-2(CO)(6)(PR(3))(2)]. The mechanistic aspects of the synthesis are discussed.
引用
收藏
页码：123 / 127
页数：5
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