MULTIPLE RADICAL ADDITIONS STARTING WITH IMINYL RADICALS DERIVED FROM SULFENYLIMINES

被引:34
|
作者
BOIVIN, J [1 ]
FOUQUET, E [1 ]
ZARD, SZ [1 ]
机构
[1] ECOLE POLYTECH,CNRS,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE
关键词
D O I
10.1016/S0040-4039(00)94438-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Iminyl radicals obtained by tri-n-butylstannane induced cleavage of S-phenyl sulphenylimines readily cyclise onto suitably located double bonds. The intermediate carbon centered radical can be trapped by a variety of electron-poor olefins thus providing an entry into synthetically useful pyrroline derivatives. © 1990.
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页码:3545 / 3548
页数:4
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