A FOURIER-TRANSFORM MASS-SPECTROMETER FOR SURFACE-ANALYSIS BY LASER-INDUCED THERMAL-DESORPTION OF MOLECULAR ADSORBATES

被引：27

作者：

LAND, DP ^{[1
]}

PETTIETTEHALL, CL ^{[1
]}

SANDER, D ^{[1
]}

MCIVER, RT ^{[1
]}

HEMMINGER, JC ^{[1
]}

机构：

[1] UNIV CALIF IRVINE,INST SURFACE & INTERFACE SCI,IRVINE,CA 92717

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 1990年 / 61卷 / 06期

关键词：

D O I：

10.1063/1.1141131

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

A Fourier transform mass spectrometer (FTMS) for ultrahigh-vacuum surface studies is described. The instrument incorporates standard surface analysis techniques such as Auger electron spectroscopy (AES), low-energy electron diffraction (LEED), and Ar ion sputtering, along with laser-induced thermal desorption (LITD) and thermal desorption spectroscopy (TDS) using FTMS detection, to perform surface analysis of metal samples. The manipulator allows temperature control of the samples between 110 and 1300 K. Using the LITD/FTMS surface reaction intermediates and kinetics are studied for the dehydrogenation of ethylene and cyclohexane on Pt(111). Relative sensitivities between AES and LITD/FTMS are discussed.

引用

页码：1674 / 1684

页数：11

共 50 条

[11] KINETICS AND MECHANISM OF BENZENE FORMATION FROM ACETYLENE ON PD(111) STUDIED BY LASER-INDUCED THERMAL-DESORPTION FOURIER-TRANSFORM MASS-SPECTROMETRY
ABDELREHIM, IM
THORNBURG, NA
SLOAN, JT
CALDWELL, TE
LAND, DP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (37) : 9509 - 9514
[12] CHARACTERIZATION OF THIN-FILMS AND SURFACE ADSORBATES BY LASER-INDUCED THERMAL-DESORPTION WITH FTMS DETECTION
MCIVER, RT
LAND, DP
HEMMINGER, JC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 84 - ANYL
[13] A NEW FOURIER-TRANSFORM MASS-SPECTROMETER WITH A SUPERCONDUCTING MAGNET
ALLEMANN, M
KELLERHALS, H
WANCZEK, KP
CHEMICAL PHYSICS LETTERS, 1980, 75 (02) : 328 - 331
[14] APPLICATION OF A MICROCOMPUTER BASED FOURIER-TRANSFORM MASS-SPECTROMETER
BUCKLEY, TJ
DOYLE, RJ
EYLER, JR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 181 (MAR): : 36 - PHYS
[15] CHEMICAL IONIZATION OF LASER-DESORBED NEUTRALS IN A FOURIER-TRANSFORM MASS-SPECTROMETER
AMSTER, IJ
LAND, DP
HEMMINGER, JC
MCIVER, RT
ANALYTICAL CHEMISTRY, 1989, 61 (02) : 184 - 186
[16] LASER DESORPTION FOURIER-TRANSFORM MASS-SPECTROMETRY AS A PROBE OF MOLECULAR ADSORBATES ON METAL-SURFACES IN UHV
SHERMAN, M
KINGSLEY, JR
MCIVER, RT
HEMMINGER, JC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 188 (AUG): : 20 - COLL
[17] ANALYSIS OF HIGH-MASS BIOMOLECULES USING ELECTROSTATIC FIELDS AND MATRIX-ASSISTED LASER DESORPTION/IONIZATION IN A FOURIER-TRANSFORM MASS-SPECTROMETER
YAO, J
DEY, M
PASTOR, SJ
WILKINS, CL
ANALYTICAL CHEMISTRY, 1995, 67 (20) : 3638 - 3642
[18] MATRIX-ASSISTED LASER-DESORPTION IONIZATION WITH AN EXTERNAL ION-SOURCE FOURIER-TRANSFORM MASS-SPECTROMETER
MCIVER, RT
LI, YZ
HUNTER, RL
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1994, 8 (03) : 237 - 241
[19] APPLICATION OF THE DUAL-CELL FOURIER-TRANSFORM MASS-SPECTROMETER
CODY, RB
KINSINGER, JA
ACS SYMPOSIUM SERIES, 1987, 359 : 59 - 80
[20] CHEMICAL-ANALYSIS USING A TRIPLE ANALYZER AND A FOURIER-TRANSFORM MASS-SPECTROMETER
GROSS, ML
WILKINS, CL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 181 (MAR): : 77 - ANYL

← 1 2 3 4 5 →