ION-BEAM IRRADIATION EFFECT ON GAS PERMEATION PROPERTIES OF POLYIMIDE FILMS

被引:21
|
作者
XU, XL
DOLVECK, JY
BOITEUX, G
ESCOUBES, M
MONCHANIN, M
DUPIN, JP
DAVENAS, J
机构
[1] UNIV LYON 1,ETUD MAT PLAST & BIOMAT LAB,CNRS,URA 507,F-69622 VILLEURBANNE,FRANCE
[2] UNIV LYON 1,DEPT PHYS MAT,CNRS,URA 172,F-69622 VILLEURBANNE,FRANCE
关键词
D O I
10.1002/app.1995.070550110
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This study deals with the ion beam irradiation effect on gas permeation properties of polyimide films. 2 MeV alpha, 500 keV, and 170 keV N+ ions were used for modifying the membranes. It was found that there are two different effects according to the implanatation dose. In the case of small-dose irradiation, ion implantation causes a raise of permeability both for CH4 and H2. When the implantation dose reaches a more important level, the implanted membranes have at the same time high permselectivity for H2/CH4 and high permeability for H2. The relationships between the permeation properties and microstructure of the films are also discussed. (C) 1995 John Wiley & Sons, Inc.
引用
收藏
页码:99 / 105
页数:7
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