THE SYNTHESIS OF DIFFERENT PLATINUM-PARTICLE GEOMETRIES BY THE CHEMICAL-REDUCTION OF CHLOROPLATINIC ACID

被引:6
|
作者
VANRHEENEN, PR [1 ]
MCKELVY, MJ [1 ]
GLAUNSINGER, WS [1 ]
机构
[1] ARIZONA STATE UNIV,DEPT CHEM,TEMPE,AZ 85287
关键词
PLATINUM COMPOUNDS - Physical Properties;
D O I
10.1016/0038-1098(86)90168-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Small platinum-particles have been synthesized in the form of spheres, chains, and composites by the chemical reduction of chloroplatinic acid. The morphology and size of the platinum particles depends on the nature of the reducing agent, presence and type of a protective agent as well as the reaction conditions. Polyvinylpyrrolidone was found to be the optimum protective agent due to its low protective ratio and high purity. The potential of this chemical-reduction approach is outlined. Investigations of the chemical and physical properties of these materials are encouraged.
引用
收藏
页码:865 / 868
页数:4
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