DIASTEREOSELECTIVE DIELS-ALDER REACTIONS BETWEEN SUBSTITUTED 1,3-BUTADIENES AND N-ALPHA-METHYLBENZYLMALEIMIDE

被引：34
|
作者：
BALDWIN, SW
GREENSPAN, P
ALAIMO, C
MCPHAIL, AT
机构：
[1] Department of Chemistry Duke University Durham
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期
关键词：
D O I：
10.1016/S0040-4039(00)79415-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The TiCl4 catalyzed reaction between 2-t-butyl-1,3-butadiene and N-alpha-methylbenzylmaleimide at -65-degrees-C affords diastereomeric Diels-Alder adducts in a 15:1 ratio. The structure of the major adduct was determined by x-ray.
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页码：5877 / 5880
页数：4
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