CYCLIC POLYMERS SWOLLEN IN A GOOD SOLVENT DYNAMIC SCATTERING PROPERTIES

被引：0
|
作者：
BENMOUNA, M
BORSALI, R
RINAUDO, M
机构：
[1] CERMAV,CNRS,BP 53X,F-38041 GRENOBLE,FRANCE
[2] UNIV JOSEPH FOURIER,F-38041 GRENOBLE,FRANCE
来源：
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1994年 / 32卷 / 06期
关键词：
SWOLLEN RINGS; DYNAMICAL RELAXATIONS; 1ST CUMULANT; OSEEN TENSOR; HYDRODYNAMIC SCREENING; INTERACTION PARAMETERS; CRITICAL EXPONENT; CONCENTRATION FLUCTUATIONS;
D O I：
10.1002/polb.1994.090320603
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A general formalism for the dynamic scattering properties of cyclic polymers in good solvent conditions is presented. Single-chain dynamics are investigated in the framework of the Oseen tensor model with and without the preaveraging approximation. The chain swelling due to excluded volume interactions is introduced by a renormalization of the internal chain statistics of cyclic polymers. The relaxations of the concentration fluctuations are also described for both ring homopolymers and copolymers. (C) 1994 John Wiley & Sons, Inc.
引用
收藏
页码：985 / 991
页数：7
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