CATALYTIC-HYDROGENATION OF 1,4-BENZOQUINONE INTO HYDROQUINONE

被引：0
|
作者：
RYBIN, AG
SLASHCHININA, TV
ZILBERMAN, EN
BOMBINA, MA
机构：
来源：
KINETICS AND CATALYSIS | 1991年 / 32卷 / 03期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogenation of 1,4-benzoquinone was investigated at 25-50-degrees-C and atmospheric pressure on Raney nickel in an aqueous medium. It was shown that in addition to hydroquinone, cyclohexanol and oligomers are formed during hydrogenation. Treating the catalyst with sulfur-containing compounds [(5-9).10(-5) g of sulfur per 1 g of Ni(Ra)) inhibits hydrogenation of the aromatic ring and increases the yield of hydroquinone.
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页码：688 / 690
页数：3
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