DIPHENYLPHOSPHINOMETHANIDE COMPLEXES OF CHROMIUM(II) AND SAMARIUM(III) - PREPARATION AND CHARACTERIZATION OF THE DINUCLEAR [CR(PH(2)PC(H)PPH(2))(2)](MU-CL)[MU-C(H)(PPH(2))(2)][CR(PH(2)PC(H)PPH(2))] AND MONONUCLEAR PSEUDO-ALLYLIC SM[ETA(3)-PH(2)PC(H)PPH(2)](3)

被引：21

作者：

HAO, SK ^{[1
]}

SONG, JI ^{[1
]}

AGHABOZORG, H ^{[1
]}

GAMBAROTTA, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 02期

关键词：

D O I：

10.1039/c39940000157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of lithium bis(diphenylphosphino)methanide with CrCl2(thf)(2) and SmCl3(thf)(3) led to the formation of an unprecedented dinuclear mixed-coordination complex [Cr{Ph(2)PC(H)PPh(2)}(2)](mu-Cl)[mu-C(H)(PPh(2))(2)][Cr{Ph(2)PC(H)PPh(2)}] 1 and mononuclear Sm[eta(3)-Ph(2)PC(H)PPh(2)](3) 2, respectively.

引用

页码：157 / 158

页数：2

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