SYNTHESIS OF CATIONIC INDENYL-ARENE AND FLUORENYL-ARENE COMPLEXES OF RUTHENIUM

被引：0
|
作者：
KUDINOV, AR
SHULPINA, LS
PETROVSKII, PV
RYBINSKAYA, MI
机构：
来源：
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 03期
关键词：
RUTHENIUM; ARENE COMPLEXES; INDENYL COMPLEXES; FLUORENYL COMPLEXES; CYCLOHEXADIENYL COMPLEXES;
D O I：
10.1007/BF00863083
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Interaction of [Ru(eta-C6H6)Cl2]2 with indenyl- or fluorenyllithium in THF gives, together with cationic benzene complexes [Ru(eta5-C9H7)(eta-C6H6)]+ and [Ru(eta5-C13H9)(eta-C6H6)]+, the neutral cyclohexadienyl derivatives Ru(eta5-C9H7)(eta5-C6H7-C9H7) and Ru(eta5-C13H9)(eta5-C6H6-C13H9, respectively. Interaction of the cyclohexadienyl complexes with Al2O3, Ph3C+, and CF3CO2H has been studied. Reaction of Ru(eta5-C13H9)(eta5-C6H7) With CF3CO2H in the presence of an arene yields cationic cyclohexadienylarene complexes: [Ru(eta5-C13H9)(eta6-arene)]+ (arene = C6H6 or 1,3,5-Me3C6H3).
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页码：549 / 554
页数：6
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