LIPASE-CATALYZED RESOLUTION OF 2-SUBSTITUTED 3-CYCLOPENTEN-1-OL DERIVATIVES

被引：4
|
作者：
SAKAI, T
IIDA, Y
KIKUYAMA, S
TSUBOI, S
UTAKA, M
机构：
来源：
CHEMISTRY LETTERS | 1991年 / 09期
关键词：
D O I：
10.1246/cl.1991.1651
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-Oxabicyclo[3.3.0]oct-6-en-3-one, the key intermediate in the prostaglandin synthsis, was subjected to the optical resolution effectively by use of lipase after conversion to 2-[2-(t-butyldimetylsilyloxy)ethyl]-3-cyclopenten-1-yl acetate and 2-[2-(N,N-dimethylcarbamoyl)methyl]-3-cylopenten-1-yl acetate.
引用
收藏
页码：1651 / 1652
页数：2
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