IN-SITU FTIR STUDY ON THE ACTIVE OXYGEN SPECIES FOR THE CONVERSION OF METHANE TO METHANOL

被引：20
|
作者：
WANG, Y [1 ]
OTSUKA, K [1 ]
EBITANI, K [1 ]
机构：
[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN
来源：
CATALYSIS LETTERS | 1995年 / 35卷 / 3-4期
关键词：
FT-IR; OXYGEN SPECIES; METHANE; METHANOL; IRON ALUMINUM PHOSPHATE;
D O I：
10.1007/BF00807181
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In situ FTIR studies showed the generation of a peroxide species by the contact of a H-2-O-2 gas mixture or of N2O with Fe-Al-P-O catalysts at greater than or equal to 573 K. This oxygen species oxidized methane into methanol at greater than or equal to 473 K, through the formation of methoxide species on the catalysts.
引用
收藏
页码：259 / 263
页数：5
相关论文
共 50 条
  • [21] DIRECT CONVERSION OF METHANE TO METHANOL——THE EFFECT OF SENSITIZERS ON THE YIELD OF METHANOL AND THE KINETIC STUDY
    AI Wan-Dong
    QIU Fa-Li Chengdu Institute of Organic Chemistry Academia Sinica Chengdu
    [J]. Journal of Energy Chemistry, 1993, (03) : 243 - 251
  • [22] OXYGEN CATALYSIS OF NUCLEAR SPIN SPECIES CONVERSION IN SOLID METHANE
    HOPKINS, HP
    DONOHO, PL
    PITZER, KS
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (02): : 864 - &
  • [23] In-situ FTIR study of dehydration and rehydration mechanisms of natural scolecite
    Prasad, Pinnelli S. R.
    Prasad, Kanapuram Shiva
    Sreedhar, Bojja
    Murthy, Sarabu Ramana
    [J]. EUROPEAN JOURNAL OF MINERALOGY, 2006, 18 (02) : 265 - 272
  • [24] In-Situ FTIR Study of Heterogeneous Oxidation of SOA Tracers by Ozone
    Wang, Runhua
    Huang, Yajuan
    Hu, Qian
    Cao, Gang
    Zhu, Rongshu
    [J]. FRONTIERS IN ENVIRONMENTAL CHEMISTRY, 2021, 2
  • [25] Study on Thermal Oxidation of Asphalt Fractions by In-situ FTIR Analysis
    Cao, Xuejuan
    Lei, Yunbo
    Wang, Wei
    [J]. MATERIALS SCIENCE AND ENGINEERING APPLICATIONS, PTS 1-3, 2011, 160-162 : 330 - +
  • [26] In-situ FTIR study of dehydration of natural Fe-stilbite
    Prasad, PSR
    Prasad, KS
    Murthy, SR
    [J]. MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B, 2005, 158 : 813 - 820
  • [27] Further approach to kinetics study by combining TGA with in-situ FTIR
    Xiang, Junjie
    Cao, Yan
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [28] Computational study of methane to methanol conversion on metal oxide clusters
    Braun, Stephanie M.
    Arnold, Adam
    Glendening, Eric D.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 845 - 845
  • [29] Comparative Study of Diverse Copper Zeolites for the Conversion of Methane into Methanol
    Park, Min Bum
    Ahn, Sang Hyun
    Mansouri, Ali
    Ranocchiari, Marco
    van Bokhoven, Jeroen A.
    [J]. CHEMCATCHEM, 2017, 9 (19) : 3705 - 3713
  • [30] METHANE FERMENTATION OF ENERGY CROPS - MAXIMUM CONVERSION KINETICS AND IN-SITU BIOGAS PURIFICATION
    JEWELL, WJ
    CUMMINGS, RJ
    RICHARDS, BK
    [J]. BIOMASS & BIOENERGY, 1993, 5 (3-4): : 261 - 278
12345