IN-SITU FTIR STUDY ON THE ACTIVE OXYGEN SPECIES FOR THE CONVERSION OF METHANE TO METHANOL

被引：20
|
作者：
WANG, Y [1 ]
OTSUKA, K [1 ]
EBITANI, K [1 ]
机构：
[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN
来源：
CATALYSIS LETTERS | 1995年 / 35卷 / 3-4期
关键词：
FT-IR; OXYGEN SPECIES; METHANE; METHANOL; IRON ALUMINUM PHOSPHATE;
D O I：
10.1007/BF00807181
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In situ FTIR studies showed the generation of a peroxide species by the contact of a H-2-O-2 gas mixture or of N2O with Fe-Al-P-O catalysts at greater than or equal to 573 K. This oxygen species oxidized methane into methanol at greater than or equal to 473 K, through the formation of methoxide species on the catalysts.
引用
收藏
页码：259 / 263
页数：5
相关论文
共 50 条
  • [1] AN IN-SITU FTIR STUDY OF THE ELECTROCHEMICAL OXIDATION OF METHANOL AT SMALL PLATINUM PARTICLES
    CHRISTENSEN, PA
    HAMNETT, A
    MUNK, J
    TROUGHTON, GL
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 370 (1-2): : 251 - 258
  • [2] In-situ ATR/FTIR observation of transformation of the nickel species in low temperature methanol synthesis.
    Ohyama, S
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U568 - U569
  • [3] In situ FTIR Study of Methanol to Hydrocarbons Conversion Process on HZSM-5 Zeolite
    Wang, Bin
    Zhang, Ying
    Guo, Guangsheng
    [J]. APPLICATION OF CHEMICAL ENGINEERING, PTS 1-3, 2011, 236-238 : 958 - +
  • [4] VOLTAMMETRIC AND IN-SITU FTIR SPECTROSCOPIC STUDY OF THE OXIDATION OF METHANOL ON PT(HKL) IN ALKALINE MEDIA
    MORALLON, E
    RODES, A
    VAZQUEZ, JL
    PEREZ, JM
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 391 (1-2): : 149 - 157
  • [5] A STUDY ON THE DIRECT CONVERSION OF METHANE TO METHANOL
    Sohrabi, Morteza
    Vafajoo, Leila
    [J]. JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2009, 54 (02) : 129 - 133
  • [6] In-situ FTIR-diffuse deflection study of methanol oxidation mechanisms on fuel cell anodes
    Fan, QB
    Pu, C
    Smotkin, ES
    [J]. IECEC 96 - PROCEEDINGS OF THE 31ST INTERSOCIETY ENERGY CONVERSION ENGINEERING CONFERENCE, VOLS 1-4, 1996, : 1112 - 1116
  • [7] In situ generation of active •OH on Co-SrTiO3 tandem catalyst for conversion of methane to methanol
    Luo, Zhongbin
    Peng, Yung-Kang
    Xiong, Haifeng
    [J]. CHEM, 2022, 8 (06): : 1545 - 1547
  • [8] The Production of Methane, Acetone, "Cold" CO and Oxygenated Species from IsoPropyl Alcohol in a Non-Thermal Plasma: An In-Situ FTIR Study
    Christensen, Paul A.
    Mashhadani, Z. T. A. W.
    Ali, Abd Halim Bin Md
    Carroll, Michael A.
    Martin, Philip A.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 122 (17): : 4273 - 4284
  • [9] In-situ FTIR study on effect of lathanum on oxidation mechanism of methanol automobile exhaust on supported palladium catalyst
    Wang, XY
    Wan, Y
    Lu, GZ
    Li, TC
    [J]. JOURNAL OF RARE EARTHS, 2002, 20 (04) : 268 - 272
  • [10] In-Situ FTIR Study on Effect of Lathanum on Oxidation Mechanism of Methanol Automobile Exhaust on Supported Palladium Catalyst
    王幸宜
    万颖
    卢冠忠
    李庭琛
    [J]. Journal of Rare Earths, 2002, (04) : 268 - 272
12345