CATALYTIC AND TPD STUDY OF OXIDATION OF N-BUTANE ON VANADIUM-OXIDE MONOLAYER CATALYSTS

被引：0
|
作者：
DEREWINSKI, M [1 ]
HABER, J [1 ]
KOZLOWSKI, R [1 ]
ZAZHIGALOV, WA [1 ]
ZAJCEV, JP [1 ]
BACHERIKOWA, IW [1 ]
BELOUSOV, WM [1 ]
机构：
[1] UKRAINIAN ACAD SCI,INST PHYS CHEM,KIEV 252028,UKRAINE,USSR
来源：
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY | 1991年 / 39卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Butane oxidation was studied for the vanadia layer supported on silica and different kinds of titania. A high selectivity to acetic acid was found for the titania based systems for temperature as low as 200-degrees-C. On the V2O5 SUPported on SiO2, maleic anhydride was a major partial oxidation product. The TPD study of the adsorbed butane revealed two kinds of oxygen species present on the surface of supported V2O5. Reactive labile oxygen species are postulated to oxidize adsorbed butane molecule at low temperature. The observed decomposition of the oxygenated adsorbed hydrocarbon at higher temperatures must proceed at the expense of the lattice oxygen of the vanadia layer.
引用
收藏
页码：403 / 409
页数：7
相关论文
共 50 条
  • [21] Catalytic partial oxidation of n-butane over Rh catalysts for solid oxide fuel cell applications
    Seyed-Reihani, Seyed-A
    Jackson, Gregory S.
    CATALYSIS TODAY, 2010, 155 (1-2) : 75 - 83
  • [22] EFFECT OF WATER ON THE CATALYTIC-OXIDATION OF TOLUENE OVER VANADIUM-OXIDE CATALYSTS
    ZHU, JM
    ANDERSSON, SLT
    APPLIED CATALYSIS, 1989, 53 (2-3): : 251 - 262
  • [23] Synthesis of Vanadium Phosphorus Oxide Catalysts Assisted by Deep-Eutectic Solvents for n-Butane Selective Oxidation
    He, Bin
    Li, Zihang
    Zhang, Huiling
    Dai, Fei
    Li, Kang
    Liu, Ruixia
    Zhang, Suojiang
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (08) : 2857 - 2867
  • [24] Investigation of the mechanism of n-butane oxidation on vanadium phosphorus oxide catalysts:: Evidence from isotopic labeling studies
    Chen, B
    Munson, EJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (08) : 1638 - 1652
  • [25] Effect of promoters for n-butane oxidation to maleic anhydride over vanadium–phosphorus‐oxide catalysts: comparison with supported vanadia catalysts
    V.V. Guliants
    J.B. Benziger
    S. Sundaresan
    I.E. Wachs
    A.M. Hirt
    Catalysis Letters, 1999, 62 : 87 - 91
  • [26] ELECTRON-SPIN RESONANCE OF VANADIUM-OXIDE MONOLAYER CATALYSTS
    FIERRO, JLG
    GAMBARO, LA
    GONZALEZELIPE, AR
    SORIA, J
    COLLOIDS AND SURFACES, 1984, 11 (1-2): : 31 - 38
  • [27] In situ diffuse reflectance spectroscopic study of supported vanadium oxide catalysts during ethane, n-butane and methanol oxidation reactions.
    Gao, XT
    Wachs, IE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U688 - U688
  • [28] Catalytic property of vanadyl pyrophosphates for selective oxidation of n-butane at high n-butane concentrations
    Kamiya, Y
    Nishikawa, E
    Okuhara, T
    Hattori, T
    APPLIED CATALYSIS A-GENERAL, 2001, 206 (01) : 103 - 112
  • [29] Effect of promoters for n-butane oxidation to maleic anhydride over vanadium-phosphorus-oxide catalysts:: comparison with supported vanadia catalysts
    Guliants, VV
    Benziger, JB
    Sundaresan, S
    Wachs, IE
    Hirt, AM
    CATALYSIS LETTERS, 1999, 62 (2-4) : 87 - 91
  • [30] Vanadium nitride catalysts:: Synthesis and evaluation for n-butane dehydrogenation
    Kwon, H
    Choi, S
    Thompson, LT
    JOURNAL OF CATALYSIS, 1999, 184 (01) : 236 - 246
12345