THE THERMAL STUDY OF ZN(II), CD(II), HG(II), PD(II), PT(II) AND AU(III) COMPLEXES OF 4,6-DIMETHYL-2-THIOPYRIMIDINE

被引：4
|
作者：
GODINOSALIDO, ML
GUTIERREZVALERO, MD
LOPEZGARZON, R
BERNALTEGARCIA, A
机构：
[1] FAC CIENCIAS EXPTL,DEPT QUIM INORGAN,E-23071 JAEN,SPAIN
[2] UNIV EXTREMADURA,FAC CIENCIAS,DEPT QUIM INORGAN,BADAJOZ,SPAIN
来源：
THERMOCHIMICA ACTA | 1993年 / 230卷
关键词：
D O I：
10.1016/0040-6031(93)80362-E
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The thermal decompositions of the 4,6-dimethyl-2-thiopyrimidine complexes Zn(DMTP)2Cl2, Cd(DMTP)2Cl2, HgDMTPCl2, Pt(DMTP)2Cl2, Pd(DMTP)2Cl2, and AuDMTPCl3 have been studied in air atmosphere by thermogravimetric and differential scanning calorimetric techniques. IR spectroscopy was used for the characterization of the intermediate and final products of the pyrolysis. The complexes show different thermal behaviours depending on the coordination mode of the DMTP ligands to the metal ions in the series of complexes studied. The enthalpies of several of the decomposition processes were calculated.
引用
收藏
页码：225 / 233
页数：9
相关论文
共 50 条
  • [21] POLAROGRAPHIC STUDY OF THE DIPROPYLDITHIOPHOSPHINATE COMPLEXES OF PD(II), PB(II), CD(II), AND ZN(II) IONS
    DENCHEV, ZI
    NIKOLOV, NK
    TALANTA, 1988, 35 (11) : 921 - 922
  • [22] SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES OF CR(III), MN(II), FE(III), CO(II), NI(II), CU(II), ZN(II), CD(II) AND HG(II) WITH PHENYLBUTAZONE
    SUMA, S
    SUDARSANAKUMAR, MR
    NAIR, CGR
    PRABHAKARAN, CP
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1993, 32 (01): : 67 - 70
  • [23] MONOMETHYL AND MONOETHYL VIOLURATE COMPLEXES OF ZN(II), CD(II) AND HG(II)
    MOLINA, MAR
    PEREGRIN, JMS
    RODRIGUEZ, AG
    CALAHORRO, CV
    ANALES DE QUIMICA SERIE B-QUIMICA INORGANICA Y QUIMICA ANALYTICA, 1983, 79 (03): : 507 - 509
  • [24] N-AMINORHODANINE COMPLEXES OF ZN(II), CD(II) AND HG(II)
    FABRETTI, AC
    FRANCHINI, GC
    PEYRONEL, G
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (10): : 2559 - 2562
  • [25] ZN(II),CD(II) AND HG(II) COMPLEXES OF SULFA-DRUGS
    NARANG, KK
    GUPTA, JK
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (03): : 589 - 590
  • [26] HYDROLYSIS OF PHOSPHODIESTERS WITH NI(II), CU(II), ZN(II), PD(II), AND PT(II) COMPLEXES
    DEROSCH, MA
    TROGLER, WC
    INORGANIC CHEMISTRY, 1990, 29 (13) : 2409 - 2416
  • [27] TRIPHENYLPHOSPHINE SELENIDE COMPLEXES OF HALIDES OF ZN(II), CD(II) AND HG(II)
    MALHOTRA, KC
    MEHROTRA, G
    CHAUDHRY, SC
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1978, 16 (10): : 905 - 906
  • [28] COMPLEXES OF TERTIARY THIOAMIDES .2. COMPLEXES OF DIMETHYLTHIOFORMAMIDE WITH ZN(II), CD(II) AND HG(II)
    AARTS, AJ
    DESSEYN, HO
    HERMAN, MA
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1977, 86 (05): : 345 - 351
  • [29] Spectrophotometric determination of Zn(II), Cd(II), Hg(II), Fe(II), Co(II), Ni(II) and Cu(II) with 2-(4,6-dimethyl-2-pyrimidylazo)-1-naphthol-4-sulphonate, sodium salt
    Singh, I
    Sushma
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2000, 39 (05): : 545 - 547
  • [30] COMPLEXES OF LEWIS-BASES WITH ZN(II), CD(II), HG(II), FE(II), PD(II), CO(II), NI(II) AND CU(II) THIOCYANATES AND CYANATES
    SINGH, PP
    SHUKLA, UP
    SETH, JN
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1976, 14 (09): : 684 - 687
12345