Mechanistic studies on thiaminase I .1. The stereochemical course of the reaction

被引：9

作者：

Nicewonger, R ^{[1
]}

Rammelsberg, A ^{[1
]}

Costello, CA ^{[1
]}

Begley, TP ^{[1
]}

机构：

[1] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853

来源：

BIOORGANIC CHEMISTRY | 1995年 / 23卷 / 04期

关键词：

D O I：

10.1006/bioo.1995.1036

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Thiaminase I catalyzes the displacement of the thiazole moiety of thiamin by a wide variety of nucleophiles. In this paper, we demonstrate that this reaction proceeds with overall retention of stereochemistry. (C) 1995 Academic Press, Inc.

引用

页码：512 / 518

页数：7

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