EXOTIC STATES IN THE E-E JAHN-TELLER PROBLEM

被引：12
|
作者：
EIERMANN, H
WAGNER, M
机构：
[1] Institut für Theoretische Physik, Universität Stuttgart, 7000 Stuttgart 80
来源：
JOURNAL OF CHEMICAL PHYSICS | 1992年 / 96卷 / 06期
关键词：
D O I：
10.1063/1.462812
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Fulton-Gouterman transformation is applied to the dynamical E-e Jahn-Teller problem. This approach leads to an unconventional way of visualizing the exact eigensolutions of the problem. It turns out that in the upper energy region, eigenfunctions with unexpected behavior make their appearance ("exotic states"). They practically have no distortion in the oscillatory subspace, whereas eigenfunctions of large radial oscillatory displacement are found in their immediate energetic neighborhood. In a rough way, these exotic states may be related to the "Slonczewski resonances."
引用
收藏
页码：4509 / 4517
页数：9
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