COBALT SCHIFF-BASE COMPLEX CATALYZED SOLVOLYTIC RING-OPENING OF EPOXY COMPOUNDS

被引：4
|
作者：
MARUYAMA, K
NAKAMURA, T
NAKAMURA, S
OGINO, A
NISHINAGA, A
机构：
[1] Department of Applied Chemistry, Osaka Institute of Technology, Osaka, 535, Ohmiya 5, Asahi-ku
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 45卷 / 02期
关键词：
D O I：
10.1007/BF02070423
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Co(salen) catalyzes solvolytic ring opening of epoxy compounds in methanol to give glycol monomethyl ether derivatives. Active species is Co (salen) (OH) which is formed in situ, and its catalytic activity depends on the pKa of the conjugated acid of X in Co (salen) (X) (X = OAc, OCH2CF3, OH).
引用
收藏
页码：165 / 171
页数：7
相关论文
共 50 条
  • [31] BASE-CATALYZED RING-OPENING OF 1,2-DIPHENYLCYCLOBUTANOLS
    FORWARD, P
    HUNTER, WN
    LEONARD, GA
    PALOU, J
    WALMSLEY, D
    WATT, CIF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (05): : 931 - 935
  • [32] Nonmetal Schiff-Base Complex-Anchored Cellulose as a Novel and Reusable Catalyst for the Solvent-Free Ring-Opening Addition of CO2 with Epoxides
    Chen, Shiyu
    Pudukudy, Manoj
    Yue, Zhongxiao
    Zhang, Heng
    Zhi, Yunfei
    Ni, Yonghao
    Shan, Shaoyun
    Jia, Qingming
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (37) : 17255 - 17265
  • [33] A CYCLIC PHOSPHATE - BASE AND METAL-ION CATALYZED RING-OPENING
    WADSWORTH, WG
    WADSWORTH, WS
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 184 (SEP): : 106 - ORGN
  • [34] INTERACTION OF COBALT(II) SCHIFF-BASE COMPLEXES WITH AROMATIC NITRO-COMPOUNDS
    DAS, PK
    DAS, D
    DE, AK
    [J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1979, 56 (07) : 651 - 655
  • [35] (FLUOROALKYL)COBALT(III) SCHIFF-BASE COMPLEXES
    VANDENBERGEN, A
    MURRAY, KS
    WEST, BO
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 33 (01) : 89 - +
  • [36] OXYGENATION OF NITROALKANES WITH COBALT SCHIFF-BASE COMPLEXES
    NISHINAGA, A
    MORIKAWA, S
    YOSHIDA, K
    MATSUURA, T
    [J]. NIPPON KAGAKU KAISHI, 1988, (04) : 487 - 494
  • [37] Progress of Ring-Opening Polymerization of Cyclic Esters Catalyzed by Iron Compounds
    Wang, Yun
    Wang, Xing
    Zhang, Wenjuan
    Sun, Wen-Hua
    [J]. ORGANOMETALLICS, 2023, 42 (14) : 1680 - 1692
  • [38] OXIDATION OF A LOW-SPIN MACROCYCLIC COBALT(II)SCHIFF-BASE COMPLEX
    GREEN, M
    TAUZHER, G
    [J]. TRANSITION METAL CHEMISTRY, 1975, 1 (01) : 1 - 2
  • [39] STRUCTURAL REQUIREMENT FOR CATALYTIC ACTIVITY OF COBALT SCHIFF-BASE COMPLEX IN OXYGENATION OF ALKENES
    MARUYAMA, K
    TSUTSUI, T
    SHIOSAKI, H
    FUJII, Y
    NISHINAGA, A
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 1993, 49 (01): : 1 - 6
  • [40] Phosphine-catalyzed ring-opening reaction of cyclopropenones with dicarbonyl compounds
    Liang, Chen
    Chen, Zhibin
    Hu, Xinyue
    Yu, Shengxia
    Wang, Zhenlian
    Cheng, Jiang
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (38) : 7712 - 7716
12345