COBALT SCHIFF-BASE COMPLEX CATALYZED SOLVOLYTIC RING-OPENING OF EPOXY COMPOUNDS

被引：4
|
作者：
MARUYAMA, K
NAKAMURA, T
NAKAMURA, S
OGINO, A
NISHINAGA, A
机构：
[1] Department of Applied Chemistry, Osaka Institute of Technology, Osaka, 535, Ohmiya 5, Asahi-ku
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 45卷 / 02期
关键词：
D O I：
10.1007/BF02070423
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Co(salen) catalyzes solvolytic ring opening of epoxy compounds in methanol to give glycol monomethyl ether derivatives. Active species is Co (salen) (OH) which is formed in situ, and its catalytic activity depends on the pKa of the conjugated acid of X in Co (salen) (X) (X = OAc, OCH2CF3, OH).
引用
收藏
页码：165 / 171
页数：7
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