N2S2 MACROCYCLIC LIGANDS - SYNTHESIS AND CHARACTERIZATION OF NOVEL TRANSITION-METAL COMPLEXES OF THE TYPE [LM(SI(2)ME(6)NH)2](2+) AND [L'M(SI(2)ME(6)NH)(2)](2+)

被引：0

作者：

SIDDIQI, KS

ARJMAND, F

TABASSUM, S

ZAIDI, SAA

机构：

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel N2S2 macrocyclic ligands, L and L' [SS'-diethyl(1,3-diaminopropane)dithiocarbamate], [SS'-cyclohexyl spiro(1,3-diaminopropane)dithiocarbamate] and their complexes with Mn-II, Fe-II, Co-II, Ni-II and Cu-II have been characterized by elemental analyses, conductivity measurements, i.r., u.v.-vis. and n.m.r. spectra. The divalent transition metal complexes appear to be square planar and achieve octahedral geometry when treated with bis(trimethylsilyl)amine to yield new heterobimetallic complexes.

引用

页码：399 / 402

页数：4

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