OXIDATION OF OLEFINS WITH ALKANESULFOPERACIDS

被引：3
|
作者：
SAFIULLIN, RL
ENIKEEVA, LR
SERENKO, SY
KOMISSAROV, VD
TOLSTIKOV, GA
机构：
[1] Institute of Chemistry, Bashkir Science Center, Ural Branch, Academy of Sciences, of the USSR, Ufa
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 02期
关键词：
D O I：
10.1007/BF00965415
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkanesulfonic peracids RSO4H effectively oxidize olefins to the corresponding epoxides. The kinetics and mechanism of this reaction are studied. It was shown that both the monomer and dimer form of the peracid act as oxidizing agents. The dependence of the weight constant of the reaction of monomer RSO4H with substituted acyclic olefins on the structure of the latter is described by the Taft equation. A linear correlation is established between log k2 and the inductive constants of the substituents on the oxygen atom in the peracid.
引用
收藏
页码：280 / 284
页数：5
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