SYNTHESES AND PHYSICAL-PROPERTIES OF FERROCENE DERIVATIVES .4. A STUDY ON THE SMECTIC STRUCTURE OF FERROCENE DERIVATIVES CONTAINING A CHOLESTERYL GROUP

被引：18
|
作者：
NAKAMURA, N
ONOI, H
OIDA, T
HANASAKI, T
机构：
[1] Department of Chemistry, Ritsumeikan University, Kita-ku
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1994年 / 257卷
关键词：
FERROCENE; LIQUID CRYSTAL; TRANSITION METAL COMPLEX; CHOLESTERYL DERIVATIVES;
D O I：
10.1080/10587259408033761
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The smectic structure of ferrocene derivatives, [4-[omega-(cholesteryloxycarbonyl)alkoxycarbonyl]phenyl]- ferrocene (abbreviated to CAPF-n, n = 2, 4, 6, 8, 9, 10, and 11, the carbon number of the flexible alkyl chain), was studied by X-ray diffraction. The structure of CAPF-n having a shorter alkyl chain (n < 9) was different from that of a longer one. The derivatives containing 2,4, 6, 8, and 10 carbon atoms in the flexible alkyl chain have a double-layer structure, while the derivatives having 9, 10, and 11 carbon atoms in the alkyl chain showed a quasi single-layer structure. CAPF-10 indicated both the double-layer and the quasi single-layer structures.
引用
收藏
页码：43 / 48
页数：6
相关论文
共 50 条
  • [31] Magnetic properties of polymer LB films containing ferrocene derivatives
    Ando, Y
    Hiroike, T
    Miyazaki, T
    Aoki, A
    Miyashita, T
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 285 : 411 - 416
  • [32] ORGANOMETALLIC COMPOUNDS .4. ANALYTICAL DETERMINATION OF FERROCENE DERIVATIVES BY GAS CHROMATOGRAPHY
    TANIKAWA, K
    ARAKAWA, K
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1965, 13 (08) : 926 - +
  • [33] Study of the coordination chemistry of ferrocene-containing pyrazole derivatives with IIb group metal ions
    Hu, AG
    Zhang, LY
    Fu, NY
    Yuan, YF
    Ding, TZ
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1998, 28 (05): : 811 - 818
  • [34] Synthesis and Physical Properties of Tetrathiafulvalene Derivatives with Ferrocene-terminated Substituents
    Tatewaki, Yoko
    Mizuguchi, Kei
    Kato, Chisato
    Nishihara, Sadafumi
    Okada, Shuji
    CHEMISTRY LETTERS, 2014, 43 (07) : 1131 - 1133
  • [35] BRIDGED FERROCENES .4. INTRAMOLECULAR CYCLIZATION OF FERROCENE DERIVATIVES CONTAINING ALPHABETA-UNSATURATED CARBONYL FUNCTIONS
    BARR, TH
    WATTS, WE
    TETRAHEDRON, 1969, 25 (04) : 861 - &
  • [36] STUDY ON SYNTHESIS AND SPECTRAL PROPERTIES OF UNSYMMETRIC DIACYL FERROCENE DERIVATIVES
    ZHOU, YK
    LI, YZ
    WU, SZ
    ACTA CHIMICA SINICA, 1988, 46 (10) : 1042 - 1044
  • [37] Synthesis and physical properties of ferrocene derivatives (XX):: Crystal structure of a liquid-crystalline ferrocene derivative, 1,1′-bis [9-[4-(4-methoxyphenoxycarbonyl)phenoxy]nonyloxycarbonyl]ferrocene
    Nakamura, Naotake
    Nio, Takahiro
    Okabe, Takashi
    Donnio, Bertrand
    Guillon, Daniel
    Gallani, Jean-Louis
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2007, 466 : 3 - 12
  • [38] Anion-binding properties of two calix[4]arene derivatives containing two ferrocene imine or ferrocene amine units at the upper rim
    Shaabani, Behrouz
    Shaghaghi, Zohreh
    APPLIED ORGANOMETALLIC CHEMISTRY, 2011, 25 (04) : 317 - 322
  • [39] Synthesis, properties and crystal structures of ferrocene derivatives containing pyrazinium and quinoxalinium units
    Siemeling, Ulrich
    Tomm, Sabine
    Bruhn, Clemens
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (23) : 5056 - 5059
  • [40] FERROCENE DERIVATIVES .4. INDENYL-IRON AND TETRAHYDROINDENYL-IRON CARBONYLS
    HALLAM, BF
    PAUSON, PL
    JOURNAL OF THE CHEMICAL SOCIETY, 1958, (FEB): : 646 - 650
12345