Synthesis of Bismuth (III) Oxide Salicylate from Nitrate Solutions for Medical Purposes

被引：0

作者：

Timakova, E. V. ^{[1
]}

Yukhin, Yu. M. ^{[1
]}

Udalova, T. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Solid State Chem & Mechanochem, Siberian Branch, Ul Kutateladze 18, Novosibirsk 6300128, Russia

来源：

CHEMISTRY FOR SUSTAINABLE DEVELOPMENT | 2009年 / 17卷 / 03期

关键词：

bismuth (III) oxide salicylate; synthesis; IR and Raman spectra; thermal analysis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By means of X-ray phase analysis, IR and Raman spectroscopy, thermogravimetry and chemical analysis, precipitation of bismuth salicylate from its nitrate solutions and the interaction of trihydroxo-pentaoxohexabismuth (III) pentanitrate trihydrate [Bi6O5(OH)(3)](NO3)(5)center dot 3H(2)O with the solutions of sodium salicylate and salicylic acid were studied. The rate of nitrate ion exchange for salicylate ion depending on temperature and pH of the medium was investigated. The conditions for the formation of bismuth (III) oxide salicylate with the composition Bi(C7H5O3) I during precipitation from nitrate solutions and according to the reaction solid - solution were determined. For use as medical substances of antiulcerants and antidiarrheal agents, the reasonableness of the synthesis of this compound in the high-purity state by means of the interaction of [Bi6O5(OH)(3)](NO3)(5)center dot 3H(2)O with the solution of salicylic acid was demonstrated.

引用

页码：305 / 313

页数：9

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