SYNTHESIS OF UNSATURATED LACTONES VIA PALLADIUM-CATALYZED CYCLIZATION OF ALKENOIC ACIDS

被引：189
|
作者：
LAROCK, RC
HIGHTOWER, TR
机构：
[1] Department of Chemistry, Iowa State University, Ames
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 20期
关键词：
D O I：
10.1021/jo00072a004
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acyclic and cyclic, aliphatic or aromatic, 4- or 5-alkenoic acids cyclize in high yield to 5- or 6-membered unsaturated lactones using 5 mol % Pd (OAc) 2, 2 equiv of NaOAc, and 1 atm Of O2.
引用
收藏
页码：5298 / 5300
页数：3
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