PHASE-DIAGRAM OF THE SYSTEM LIF-NA3ALF6-NA3FSO4 - EXPERIMENTAL-STUDY AND CALCULATION

被引:5
|
作者
FELLNER, P
GABCOVA, J
机构
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D O I
10.1016/0040-6031(92)85309-J
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental data on solid-liquid phase equilibria in the binary system Na3AlF6-Na3FSO4, and ternary system LiF-Na3AlF6-Na3FSO4 are presented. A model of molten salt mixtures based on the assumption of the existence of ionic assemblies is applied to this system and the temperatures of primary crystallization of LiF, Na3AlF6 and Na3FSO4 were calculated. Good agreement between the experimental and calculated data was achieved.
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页码:321 / 326
页数:6
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