A NEXAFS STUDY OF THE ORIENTATION OF BENZOATE INTERCALATED INTO A LAYER DOUBLE HYDROXIDE

被引：6
|
作者：
MOGGRIDGE, GD [1 ]
PARENT, P [1 ]
TOURILLON, G [1 ]
机构：
[1] CTR UNIV PARIS SUD, LURE, F-91405 ORSAY, FRANCE
来源：
PHYSICA B | 1995年 / 208卷 / 1-4期
关键词：
D O I：
10.1016/0921-4526(94)00843-K
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
NEXAFS is shown to be an excellent technique, of potentially widespread application, for the determination of the orientation of organic molecules intercalated in preferentially oriented thin films of polycrystalline, layered minerals. A NEXAFS study of [Mg2Al(OH)(6)](C7H5O2-)-C-+. nH(2)O, a layered anionic clay, is described. This material shows a transition from a layer spacing of 15.4 Angstrom to only 9 Angstrom at a remarkably low temperature(below 100 degrees C). This is shown to be accompanied by a change in the angle of the plane of the benzoate molecule to the 00l planes from 35 +/- 10 degrees to 0 +/- 10 degrees.
引用
收藏
页码：269 / 270
页数：2
相关论文
共 50 条
  • [1] A NEXAFS STUDY OF THE ORIENTATION OF BENZOATE INTERCALATED INTO A LAYER DOUBLE HYDROXIDE
    MOGGRIDGE, GD
    PARENT, P
    TOURILLON, G
    [J]. CLAYS AND CLAY MINERALS, 1994, 42 (04) : 462 - 472
  • [2] Molecular modeling of layered double hydroxide intercalated with benzoate, modeling and experiment
    Petr Kovář
    M. Pospíšil
    M. Nocchetti
    P. Čapková
    Klára Melánová
    [J]. Journal of Molecular Modeling, 2007, 13 : 937 - 942
  • [3] Molecular modeling of layered double hydroxide intercalated with benzoate, modeling and experiment
    Kovar, Petr
    Pospisil, M.
    Nocchetti, M.
    Capkova, P.
    Melanova, Klara
    [J]. JOURNAL OF MOLECULAR MODELING, 2007, 13 (08) : 937 - 942
  • [4] Synthesis of the Benzoate Intercalated Layered Double Hydroxide of Nickel and Aluminum: Application of Mering's Rule
    Manohara, G. V.
    Kamath, P. Vishnu
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (02): : 434 - 438
  • [5] Synthesis of Layered Rare-Earth Hydroxide Intercalated with Benzoate Ions
    Zhang, Lin
    Jiang, Danyu
    Zhang, Na
    Xia, Jinfeng
    Li, Qiang
    [J]. SCIENCE OF ADVANCED MATERIALS, 2017, 9 (3-4) : 452 - 455
  • [6] Preparation and properties of in-situ polymerized polyurethane/stearate intercalated layer double hydroxide nanocomposites
    Kotal, Moumita
    Srivastava, Suneel Kumar
    Manu, Saraswathi Kesavapillai
    Saxena, Aravind Kumar
    Pandey, Kailash Nath
    [J]. POLYMER INTERNATIONAL, 2013, 62 (05) : 728 - 735
  • [7] The molecular orientation of polyimide alignment layer used in TFT-LCDs with NEXAFS study
    Kim, Young Jeon
    Hwang, Yong Taek
    Rho, Kyung Lae
    Nam, In Hyun
    Choi, Sunglak
    Cho, Sung-Chan
    Oh, Weon Sik
    [J]. 2008 SID INTERNATIONAL SYMPOSIUM, DIGEST OF TECHNICAL PAPERS, VOL XXXIX, BOOKS I-III, 2008, 39 : 393 - 396
  • [8] Benzoate anions-intercalated NiFe-layered double hydroxide nanosheet array with enhanced stability for electrochemical seawater oxidation
    Zhang, Longcheng
    Liang, Jie
    Yue, Luchao
    Dong, Kai
    Li, Jun
    Zhao, Donglin
    Li, Zerong
    Sun, Shengjun
    Luo, Yongsong
    Liu, Qian
    Cui, Guanwei
    Alshehri, Abdulmohsen Ali
    Guo, Xiaodong
    Sun, Xuping
    [J]. Nano Research Energy, 2022, 1 (03):
  • [9] Layered Double Hydroxide Intercalated with Sodium Dodecyl Sulfate
    Moyo, Lumbidzani
    Focke, Walter W.
    Labuschagne, Frederick J. W. J.
    Verryn, Sabine
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2012, 555 : 51 - 64
  • [10] Methotrexate intercalated ZnAl-layered double hydroxide
    Chakraborty, Manjusha
    Dasgupta, Sudip
    Soundrapandian, Chidambaram
    Chakraborty, Jui
    Ghosh, Swapankumar
    Mitra, Manoj K.
    Basu, Debabrata
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2011, 184 (09) : 2439 - 2445
12345