Synthesis of the Benzoate Intercalated Layered Double Hydroxide of Nickel and Aluminum: Application of Mering's Rule

被引：7
|
作者：
Manohara, G. V. [1 ]
Kamath, P. Vishnu [1 ]
机构：
[1] Bangalore Univ, Dept Chem, Cent Coll, Bangalore 560056, Karnataka, India
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 02期
关键词：
ANIONIC CLAYS; TEREPHTHALATE; RELEASE; ACID; LDH;
D O I：
10.1002/zaac.201300275
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Homogeneous precipitation from a mixed metal nitrate solution using benzamide as a hydrolysis agent results in the formation of a benzoate-intercalated layered double hydroxide of nickel and aluminum with a basal spacing of 15.6 Å. The alternation in the line widths of the basal reflections has been shown to arise by the random interstratification of a 8.8 Å phase with an altered orientation of the benzoate ions. This work is an illustration of the application of Mering's rules to model disorder in layered double hydroxides. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：434 / 438
页数：5
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