ALPHA-DISTONIC IONS AS TRANSIENT SPECIES IN THE REACTIONS OF METASTABLE ALKYL BENZOATE RADICAL CATIONS

被引：6
|
作者：
AUDIER, HE
MILLIET, A
SOZZI, G
HAMMERUM, S
机构：
[1] ECOLE POLYTECH, DEPT CHIM, F-91128 PALAISEAU, FRANCE
[2] UNIV COPENHAGEN, HC ORSTED INST, DEPT GEN ORGAN CHEM, DK-2100 COPENHAGEN, DENMARK
来源：
ORGANIC MASS SPECTROMETRY | 1990年 / 25卷 / 01期
关键词：
D O I：
10.1002/oms.1210250110
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The key intermediates to the fragmentation of metastable methyl and ethyl benzoate radical cations are α‐ and β‐distonic isomers of the molecular ions. The α‐distocic isomers are also formed by fragmentation of longer chain alkyl benzoates, but may not be long‐lived, stable species. Rearrangement of the α‐distonic ions prior to fragmentation can take place, but (re)formation of the benzoate molecular ions does not occur. Copyright © 1990 John Wiley & Sons, Ltd.
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页码：44 / 48
页数：5
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