DETERMINATION OF CHLORIDE-ION DIFFUSION-COEFFICIENTS FOR ZINC DISSOLUTION IN A LOW-TEMPERATURE MOLTEN-SALT

被引：5

作者：

SIMONSEN, LR

DONAHUE, FM

机构：

[1] Chemical Engineering Department, The University of Michigan, Ann Arbor

来源：

ELECTROCHIMICA ACTA | 1990年 / 35卷 / 01期

关键词：

D O I：

10.1016/0013-4686(90)85042-L

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The transport properties and stoichiometry of the zinc dissolution process in mixtures of aluminum chloride and 1-methyl-3-ethylimidazolium chloride were studied. A new mass transfer correlation for rotating cylinder electrodes was found for these high Schmidt number electrolytes. Two limiting current regions were observed during the dissolution process which corresponded to a coordination number of four at low overpotentials and a coordination number of three at high overpotentials. The quantity Dμ/T was calculated to be 3.5 × 10-10, which corresponds to a chloride ion radius of 2.1 × 10-8 cm. © 1990.

引用

页码：89 / 92

页数：4

共 50 条

[31] Novel supported low-temperature solid molten salt (SMS) anode materials for Li-ion batteries
Jiang, Lei
Han, Ning
Luo, Tingting
Zhang, Zhe
Liang, Fenghao
Wu, Daoning
Li, Xiaochun
Liu, Fengjiao
Rui, Yichuan
Zhang, Wei
Qu, Yi
Tang, Bohejin
CHEMICAL ENGINEERING JOURNAL, 2023, 458
[32] Preparation and Electrochemical Properties of LiCuxMn2-xO4 (x ≤ 0.10) Cathode Material by a Low-Temperature Molten-Salt Combustion Method
Huang, Jijun
Li, Qiling
Bai, Hongli
Xu, Wangqiong
He, Yonghui
Su, Changwei
Peng, Jinhui
Guo, Junming
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2015, 10 (06): : 4596 - 4603
[33] THE CHEMISTRY OF THE RECHARGEABLE LOW-TEMPERATURE MOLTEN-SALT CELL NA-BETA''-ALUMINA/SCL3+IN ALCL3-NACL
MAMANTOV, G
MARASSI, R
TANEMOTO, K
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (08) : C339 - C339
[34] Stability of new Ag/AgCl reference electrode with NZSP ceramic membrane in low-temperature sodium ion molten salt
Tu J.-G.
Chang C.
Feng X.
Luo Y.-W.
Meng L.
Jiao S.-Q.
Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals, 2023, 33 (12): : 4181 - 4188
[35] Low-Temperature Molten-Salt-Assisted Recovery of Valuable Metals from Spent Lithium-Ion Batteries
Fan, Ersha
Li, Li
Lin, Jiao
Wu, Jiawei
Yang, Jingbo
Wu, Feng
Chen, Renjie
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (19) : 16144 - 16150
[36] Preparation and Electrochemical Performance of Nano-LiNi0.05Mn1.95O4 Cathode Materials by a Low-Temperature Molten-Salt Combustion Method
Xu, Wangqiong
Bai, Hongli
Li, Qiling
Feng, Tao
Guo, Junming
Feng, Lili
Su, Chang-Wei
Bai, Wei
Liu, Xiaofang
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (10): : 9758 - 9773
[37] Low-Temperature Rapid Synthesis of Rod-Like ZrB2 Powders by Molten-Salt and Microwave Co-Assisted Carbothermal Reduction
Liu, Jianghao
Huang, Zhong
Huo, Chaoge
Li, Faliang
Zhang, Haijun
Zhang, Shaowei
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2016, 99 (09) : 2895 - 2898
[38] RECHARGEABLE HIGH-VOLTAGE LOW-TEMPERATURE MOLTEN-SALT CELL NA/BETA''-ALUMINA/SCL3+ IN ALCL3-NACL
MAMANTOV, G
HVISTENDAHL, J
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 168 (1-2): : 451 - 466
[39] Boosting Li-Ion Conductivity of Fluoride Solid Electrolyte by Low-Temperature Molten Salt Ablation and Particle Boundary Doping
Nie, Xianhui
Lei, Meng
Hu, Jiulin
Li, Chilin
ACS NANO, 2024, 18 (43) : 30099 - 30112
[40] INSITU RAMAN-SPECTROSCOPIC STUDIES OF THE RECHARGEABLE LOW-TEMPERATURE MOLTEN-SALT CELL - NA/BETA''-ALUMINA/S(IV) IN ALCL3-NACL
TANEMOTO, K
KATAGIRI, A
MAMANTOV, G
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (04) : 890 - 892

← 1 2 3 4 5 →