IMPLICATIONS OF A TRANSITION-STATE IN A DIELS-ALDER REACTION IN SUPERCRITICAL CARBON-DIOXIDE

被引：9

作者：

IKUSHIMA, Y ^{[1
]}

SAITO, N ^{[1
]}

SATO, O ^{[1
]}

ARAI, M ^{[1
]}

机构：

[1] TOHOKU UNIV, INST CHEM REACT SCI, AOBA KU, SENDAI, MIYAGI 980, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 06期

关键词：

D O I：

10.1246/bcsj.67.1734

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synopsis. For the Diels-Alder reaction between isoprene and methyl acrylate in supercritical carbon dioxide at 323 K, the solubility parameter of the activated complex was determined as a function of the pressure, ranging from 7 to 20 MPa, in order to study the nature of the complex and the effect of the solvent on the reaction. The relation between the solubility parameter and the E(T)(30)-scale was examined as well.

引用

页码：1734 / 1736

页数：3

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