IMPLICATIONS OF A TRANSITION-STATE IN A DIELS-ALDER REACTION IN SUPERCRITICAL CARBON-DIOXIDE

被引：9
|
作者：
IKUSHIMA, Y [1 ]
SAITO, N [1 ]
SATO, O [1 ]
ARAI, M [1 ]
机构：
[1] TOHOKU UNIV, INST CHEM REACT SCI, AOBA KU, SENDAI, MIYAGI 980, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 06期
关键词：
D O I：
10.1246/bcsj.67.1734
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synopsis. For the Diels-Alder reaction between isoprene and methyl acrylate in supercritical carbon dioxide at 323 K, the solubility parameter of the activated complex was determined as a function of the pressure, ranging from 7 to 20 MPa, in order to study the nature of the complex and the effect of the solvent on the reaction. The relation between the solubility parameter and the E(T)(30)-scale was examined as well.
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页码：1734 / 1736
页数：3
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