THE INITIAL-STAGES OF THE OXIDATION OF AL(111) .1.

被引：17

作者：

OCONNOR, DJ ^{[1
]}

WOUTERS, ER ^{[1
]}

VANDERGON, AWD ^{[1
]}

VANDERVEEN, JF ^{[1
]}

ZAGWIJN, PM ^{[1
]}

FRENKEN, JWM ^{[1
]}

机构：

[1] FOM,INST ATOM & MOLEC PHYS,1098 SJ AMSTERDAM,NETHERLANDS

来源：

SURFACE SCIENCE | 1993年 / 296卷 / 02期

关键词：

D O I：

10.1016/0039-6028(93)91141-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Al(111) oxidation has been subjected to numerous studies using surface analysis techniques. Indeed it seems to have been used as a proving ground for techniques to establish the detail each can shed on the determination of the adsorption site of O on a clean Al(111) surface. In this first detailed ion scattering study of the oxidation of the Al(111) surface it has been established that at exposures of up to 100 L almost one monolayer of oxygen is adsorbed to the surface. This observation alone brings into question many models which conclude that the adsorption leads to a surface, and subsurface layer of oxygen. Furthermore, by using shadowing and blocking associated with medium energy ion scattering (MEIS) it has been possible to exclude the existence of a significant subsurface site at exposures up to 100 L.

引用

页码：131 / 140

页数：10

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