Synthesis and structure of aryl(hetaryl)spiropyrrolidones

被引：0
|
作者：
V. M. Berestovitskaya
I. A. Litvinov
O. S. Vasil’eva
A. A. Nikonorov
E. S. Ostroglyadov
D. B. Krivolapov
机构：
[1] A. I. Herzen State Pedagogical University of Russia,A. E. Arbuzov Institute of Organic and Physical Chemistry
[2] Kazan Scientific Center of the Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2012年 / 61卷
关键词：
2-pyrrolidones; 3,3′-spiropyrrolidones; diastereomers; catalytic hydrogenation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Hydrogenation of the diastereouniform 3-[1-aryl(hetaryl)-2-nitroethyl]-3-methoxycarb-onyl-4-phenyl(3-pyridyl)-2-pyrrolidones is accompanied by intramolecular acylation of the formed amino group to afford the diastereomerically pure 4,4′-aryl(hetaryl)-3,3′-spirobi-[2-pyrrolidones]. The structures of these diastereomers were characterized by IR, 1H and 13C NMR spectroscopy using heteronuclear correlation experiments, and X-ray diffraction study.
引用
收藏
页码：1014 / 1023
页数：9
相关论文
共 50 条
  • [41] 1-aryl(hetaryl)-2-ethoxycarbonyl-3-trimethylsiloxy-1,3-butadienes in diene synthesis. Synthesis of 2-hydroxy-4-aryl(hetaryl)-9,10-anthraquinone derivatives
    Shults, EE
    Petrova, TN
    Rybalova, TV
    Gatilov, YV
    Tolstikov, GA
    ZHURNAL ORGANICHESKOI KHIMII, 1998, 34 (06): : 895 - 906
  • [42] FISCHER CYCLIZATION OF N,N-DIARYL-HETARYL (AND N-ARYL-HETARYL)HYDRAZINES
    SHARKOVA, NM
    KUCHEROV.NF
    ZAGOREVS.VA
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1974, (11): : 1580 - 1581
  • [43] Plant coumarins: VIII. Suzuki reaction in the synthesis of 3-aryl(hetaryl)furocoumarins
    A. V. Lipeeva
    E. E. Shul’ts
    M. M. Shakirov
    G. A. Tolstikov
    Russian Journal of Organic Chemistry, 2011, 47 : 1404 - 1409
  • [44] Synthesis, anticancer activity, and COMPARE analysis of N-trifluoromethylalkyl-N′-aryl/hetaryl ureas
    Popov, Anatoliy V.
    Luzina, Elena L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [45] Improved synthesis of tertiary propargyl alcohols by the Favorskii reaction of alkyl aryl (hetaryl) ketones with acetylene
    Shmidt, E. Yu.
    Bidusenko, I. A.
    Protsuk, N. I.
    Mikhaleva, A. I.
    Trofimov, B. A.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 49 (01) : 8 - 11
  • [46] NEW EFFICIENT SYNTHESIS OF METHYL TRANS-2-ARYL (OR HETARYL)-1-BENZAMIDOCYCLOPROPANCARBOXYLATES
    BLASCO, J
    CATIVIELA, C
    DEVILLEGAS, MDD
    SYNTHETIC COMMUNICATIONS, 1987, 17 (13) : 1549 - 1557
  • [47] Synthesis of 1-Substituted 3-Aryl-5-aryl(hetaryl)-2-pyrazolines and Study of Their Antitumor Activity
    Insuasty, Braulio
    Chamizo, Leidy
    Munoz, Jhon
    Tigreros, Alexis
    Quiroga, Jairo
    Abonia, Rodrigo
    Nogueras, Manuel
    Cobo, Justo
    ARCHIV DER PHARMAZIE, 2012, 345 (04) : 275 - 286
  • [48] Plant coumarins: VIII. Suzuki reaction in the synthesis of 3-aryl(hetaryl)furocoumarins
    Lipeeva, A. V.
    Shul'ts, E. E.
    Shakirov, M. M.
    Tolstikov, G. A.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 47 (09) : 1404 - 1409
  • [49] Improved synthesis of tertiary propargyl alcohols by the Favorskii reaction of alkyl aryl (hetaryl) ketones with acetylene
    E. Yu. Shmidt
    I. A. Bidusenko
    N. I. Protsuk
    A. I. Mikhaleva
    B. A. Trofimov
    Russian Journal of Organic Chemistry, 2013, 49 : 8 - 11
  • [50] Synthesis and properties of 2-alkoxy- and 2-alkylthio-3-aryl(hetaryl)propenals
    Keiko, Natalia A.
    Stepanova, Ludmila G.
    Verochkina, Ekaterina A.
    Larina, Ludmila I.
    ARKIVOC, 2010, : 49 - 60
12345