Interaction of [Mo6Cl14]2− with H2Se: Selective Preparation of [Mo6SeCl13]3−

被引：0

作者：

Pavel A. Abramov

Maxim N. Sokolov

Alexandr V. Virovets

Eugenia V. Peresypkina

Cristian Vicent

Vladimir P. Fedin

机构：

[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry

[2] Novosibirsk State University,undefined

[3] Universitat Jaume I,undefined

来源：

Journal of Cluster Science | 2009年 / 20卷

关键词：

Molybdenum; Selenium; Chlorocomplexes; Clusters; Crystal structure; ESI mass-spectrometry;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Reaction of [Mo6(μ3-Cl)8Cl6]2− with H2Se, generated in situ from ZnSe and 4 M HCl under hydrothermal conditions lead to the substitution of one or two bridging chlorides, depending on the reagents ratio. With the Mo6/ZnSe 1:3 molar ratio [Mo6(μ3-SeCl7)Cl6]3− forms selectively in high yield. Further substitution is more hindered, and even at 1:20 cluster-to-selenide molar ratio a mixture of [Mo6(μ3-SeCl7)Cl6]3− and [Mo6(μ3-Se2Cl6)Cl6]4− is formed. The products were characterized by X-ray, Raman spectra and electrospray ionization mass spectrometry.

引用

页码：83 / 92

页数：9

共 50 条

[41] Simulation of crystal and electronic structures of octahedral molybdenum cluster complex compound Cs2[Mo6Cl14] using various DFT functionals
Saito, Norio
Lemoine, Pierric
Cordier, Stephane
Ohsawa, Takeo
Wada, Yoshiki
Grasset, Fabien
Cross, Jeffrey Scott
Ohashi, Naoki
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2017, 125 (10)
[42] ELECTRONIC-STRUCTURE OF STRUCTURAL OPEN DERIVATIVES OF THE [MO6X14]2--CLUSTER - [MO5CL13]2- AND [MO4I11]2-
MIESSNER, H
KOROLKOV, DV
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 496 (01): : 175 - 185
[43] Donor slab robustness and band filling variations in BDT-TTP-based molecular conductors: β-(BDT-TTP)6 [Re6S6Cl8]&middot(CH2Cl-CHCl2)2 and β-(BDT-TTP)6[Mo6Cl14]&middot(CH2Cl-CHCl2)2
Deluzet, Andre, 2000, Wiley-VCH Verlag Berlin GmbH, Weinheim, Germany (12)
[44] Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]•2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]•2CH2Cl2
Sokolov, M. N.
Mikhailov, M. A.
Abramov, P. A.
Fedin, V. P.
JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (01) : 197 - 201
[45] Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2
M. N. Sokolov
M. A. Mikhailov
P. A. Abramov
V. P. Fedin
Journal of Structural Chemistry, 2012, 53 : 197 - 201
[46] INTERACTION OF MO6TE8 MOLYBDENUM TELLURIDE WITH DICHLORODISULFANE AND X-RAY-DIFFRACTION STUDY OF (ET4N)2MO6CL14
FEDIN, VP
GERASKO, OA
FEDOROV, VE
VIROVETS, AV
SLOVOKHOTOV, YL
STRUCHKOV, YT
ZHURNAL NEORGANICHESKOI KHIMII, 1990, 35 (05): : 1142 - 1145
[47] Chloroselenates with Di- and tetravalent selenium:: 77Se-NMR-spectra, syntheses, and crystal structures of (PPh4)2SeCl6•2CH2Cl2, (NMe3Ph)2SeCl6, (K-18-crown-6)2SeCl6•2CH3CN, PPh4Se2Cl9, (NEt4)2Se2Cl10, (PPh4)2Se3Cl8•CH2Cl2, and (PPh4)2Se4Cl12•CH2Cl2
Czado, W
Maurer, M
Muller, U
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (11): : 1871 - 1876
[48] Reaction of Mo（CO）6 with Alkoxide: Synthesis and Structure of the Mo（0）-OR Complex [Et4N]3[Mo2（CO）6（μ-OC6H4OCH2C6H5）3]
庄伯涛
魏强
何玲洁
周张锋
吴克琛
Chinese Journal of Structural Chemistry, 2007, (04) : 401 - 408
[49] Reaction of Mo(CO)6 with alkoxide:: Synthesis and structure of the Mo(0)-OR complex [Et4N]3[Mo2(CO)6(μ-OC6H4OCH2C6H5)3]
Zhuang Bo-Tao
Wei Qiang
He Ling-Jie
Zhou Zhang-Feng
Wu Ke-Chen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (04) : 401 - 408
[50] NORMAL COORDINATE ANALYSIS OP TRINUCLEAR MOLYBDENUM CLUSTER UNIT [Mo3OCl6]2+ IN H[Mo3O（OAc）3Cl6]·3H2O
Lin Chichang Chen GongDepartment of Chemistry
结构化学, 1986, (01) : 14 - 17

← 1 2 3 4 5 →