A new Zn(II) complex of unusual unidentate coordination of 4,4′-bipyridine, a new precursor for the preparation of zinc(II) oxide nanoparticles

被引：0
|
作者：
L. Dolatyari
P. Seddigi
A. Ramazani
M. G. Amiri
A. Morsali
机构：
[1] Islamic Azad University,Department of Chemistry, Zanjan Branch
[2] Payame Noor University,Department of Chemistry
[3] Tarbiat Modares University,Department of Chemistry, Faculty of Sciences
来源：
Journal of Structural Chemistry | 2013年 / 54卷
关键词：
zinc(II); 4,4′-bipyridine; coordination polymer; fluorescence; nanoparticles;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A 4,4′-bipyridine Zn(II) complex [Zn(4,4′-bipy)2(H2O)4](ClO4)2·4(4,4′-bipy) is synthesized, characterized by elemental analysis, IR, 1H NMR, 13C NMR spectroscopy, and studied by X-ray crystallography. The compound forms monomeric units as a result of unusual unidentate coordination of 4,4′-bipy ligands. The thermal stability of the compound is studied by thermal analyses. Furthermore, the complex is luminescent with emission maxima at 329 nm in the methanol solvent. Different sizes of zinc(II) oxide nanoparticles are prepared by calcination of the [Zn(4,4′-bipy)2(H2O)4](ClO4)2·4(4,4′-bipy) compound at two different temperatures. These nanostructures are characterized by X-ray powder diffraction and scanning electron microscopy.
引用
收藏
页码：571 / 576
页数：5
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