Acid-catalyzed disproportionation of N,N-bis(4-tert-butylphenyl)hydroxylamine. Synthesis and structure of 10-[5-tert-butyl-2-(4-tert-butylphenylamino)phenyl]-3,7-di-tert-butylphenoxazine

被引：0
|
作者：
V. A. Golubev
V. V. Tkachev
V. D. Sen’
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词：
MeCN; Hydroxylamine; Hydrazine Hydrate; Nitroxyl; Phenoxazine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New method of synthesis was developed for N,N-bis(4-tert-butylphenyl)hydroxylamine by reduction of the corresponding aminoxyl with hydrazine hydrate. At the treatment with strong acids this hydroxylamine derivative is converted in bis(4-tert-butylphenyl)amine and 10-[5-tert-butyl-2-(4-tert-butylphenylamino) phenyl]-3,7-di-tert-butylphenoxazine. The structure of the latter was established by X-ray diffraction analysis. The mechanism was suggested of the acid-catalyzed disproportionation of N,N-bis(4-tert-butylphenyl) hydroxylamine.
引用
收藏
页码：678 / 684
页数：6
相关论文
共 50 条
  • [21] Experimental Determination of Ground and Excited State Dipole Moments of N, N-Bis (2, 5-di-tert-butylphenyl)-3, 4:9, 10-perylenebis (dicarboximide) (DBPI) A Photostable Laser Dye
    S. A. El-Daly
    A. M. Asiri
    K. A. Alamry
    Journal of Fluorescence, 2014, 24 : 1307 - 1311
  • [22] Synthesis and structure of E-2-(2,4,6-tri-tert-butylphenylphosphinyl)-2-[N-(tert-butyldimethylsilyl)-N-(p-chrolophenyl)]amino-1-(2,4,6-tri-tert-butyl-phenyl)phosphacthylene
    Zhang, LX
    Pang, Z
    Zhou, XG
    Cai, RF
    Huang, ZE
    Sun, J
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (02) : 86 - 90
  • [23] Chemical and Electrochemical Syntheses, Structure, and Luminescent Properties of Zinc and Cadmium Complexes with N-{2-[(E)-(4-tert-Butylphenyl)iminomethyl]phenyl}-4-methylbenzenesulfonamide
    Lifintseva, T. V.
    Burlov, A. S.
    Vlasenko, V. G.
    Koshchienko, Yu. V.
    Mal'tsev, E. I.
    Dmitriev, A. V.
    Lypenko, D. A.
    Trigub, A. L.
    Garnovskii, D. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2018, 88 (10) : 2125 - 2132
  • [24] Crystal structure of 4-(4-tert-butylphenyl)-3,5-bis(2-pyridyl)-1,2,4-triazole, C22H21N5
    Shao, SC
    Yang, S
    Zhang, SP
    Wang, DQ
    Zhu, HL
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (03): : 259 - 260
  • [25] Chemical and Electrochemical Syntheses, Structure, and Luminescent Properties of Zinc and Cadmium Complexes with N-{2-[(E)-(4-tert-Butylphenyl)iminomethyl]phenyl}-4-methylbenzenesulfonamide
    T. V. Lifintseva
    A. S. Burlov
    V. G. Vlasenko
    Yu. V. Koshchienko
    E. I. Mal’tsev
    A. V. Dmitriev
    D. A. Lypenko
    A. L. Trigub
    D. A. Garnovskii
    Russian Journal of General Chemistry, 2018, 88 : 2125 - 2132
  • [26] Synthesis of O-ethyl-P-(3,5-di-tert-butyl-4-hydroxybenzyl)-N,N-diethylphosphonamide-the first representative of mixed α-phosphorylated 2,6-Di-tert-butyl-4-methylenecyclohexa-2,5-dienones
    Azmukhanova, R. R.
    Gibadullina, E. M.
    Pudovik, M. A.
    Burilov, A. R.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (09) : 2138 - 2140
  • [27] Synthesis of O-ethyl-P-(3,5-di-tert-butyl-4-hydroxybenzyl)-N,N-diethylphosphonamide—the first representative of mixed α-phosphorylated 2,6-Di-tert-butyl-4-methylenecyclohexa-2,5-dienones
    R. R. Azmukhanova
    E. M. Gibadullina
    M. A. Pudovik
    A. R. Burilov
    Russian Journal of General Chemistry, 2016, 86 : 2138 - 2140
  • [28] Synthesis and Structure of E-2-(2,4,6-tri tert butylphenylphosphinyl)-2-〔N-(tert-butyldimethylsilyl)-N-(p-chrolophenyl)〕amino-1-(2,4,6-tri tert-butyl-phenyl)phosphacthylene
    ZHANG Li Xin PANG Zhen * ZHOU Xi Geng CAI Rui Fang HUANG Zu En (Department of Chemistry
    Chinese Journal of Structural Chemistry, 2000, (02) : 86 - 90
  • [29] Fe(ClO4)3•xH2O-Catalysed Ritter Reaction: Synthesis of N-tert-Butyl Amides from Nitriles and Di-tert-Butyl Dicarbonate
    Feng, Chengliang
    Yan, Bin
    Yao, Wenjin
    Chen, Junqing
    Ji, Min
    CHEMISTRYSELECT, 2018, 3 (29): : 8501 - 8504
  • [30] Synthesis, structure and electrochemical properties of a cobalt(II) complex supported by 2-tetrahydrofurfurylamino-N,N-bis(2-methylene-4-tert-butyl-6-methyl)phenol
    Lin, Chen-Neng
    Zhou, Ling-Ling
    Fu, Ling-Zhi
    Zhan, Shu-Zhong
    Chen, Cai-Hong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 61 : 97 - 99
12345