Trimethylene-bridged tetraorganodistannoxanes {[Me3SiCH2(RCOO)Sn (CH2)3Sn(OOCR) CH2SiMe3]O}n (R = Ph, 2,4-Me2C6H3): Control of structure by variation of R

被引：0

作者：

Costisella B. ^{[1
]}

Dakternieks D. ^{[2
]}

Jurkschat K. ^{[1
]}

Mehring M. ^{[1
]}

Paulus I. ^{[1
]}

Scḧrmann M. ^{[1
]}

机构：

[1] Lehrstuhl fur Anorganische Chemie II der Universitat Dortmund

[2] Centre for Chiral and Molecular Technologies, Deakin University, Geelong

来源：

Chemistry of Heterocyclic Compounds | 2001年 / Kluwer Academic/Plenum Publishers卷 / 37期

关键词：

Distannoxanes; X-ray structure;

D O I：

10.1023/A:1017907419300

中图分类号：

学科分类号：

摘要：

The synthesis of trimethylene-bridged, carboxylate-substituted tetraorganodistannoxanes {[Me3SiCH2(RCOO)Sn (CH2)3Sn(OOCR)CH2 SiMe3]O}n (1, R = Ph; 2, R = 2,4-Me2C6H3) is reported. Depending on the structure of R, in the solid state these compounds are either dimers (1, n = 2, cis-isomer) with a ladder-type structure or tetramers (2, n = 4) with a double ladder-type structure.

引用

页码：1405 / 1417

页数：12

共 50 条

[21] SYNTHESIS AND CHARACTERIZATION OF INDIUM-ARSENIC COMPOUNDS CONTAINING A 4-MEMBERED IN-AS-IN-AS OR IN-AS-IN-CL RING - CRYSTAL-STRUCTURES OF [(ME3SICH2)2INAS(SIME3)2]2 AND (ME3SICH2)2INAS(SIME3)2IN(CH2SIME3)2CL
WELLS, RL
JONES, LJ
MCPHAIL, AT
ALVANIPOUR, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 391 - INOR
[22] Silanediols derived from silanetriols. X-ray crystal structures of (2,4,6-Me(3)C(6)H(2))N(SiMe(3))Si(OSiMe(3))(OH)(2) and (2,4,6-Me(3)C(6)H(2))N(SiMe(3))Si(OSiMe(2)R)(OH)(2) [R=CH2(2-NH2-3,5-Me(2)C(6)H(2))]
Murugavel, R
Voigt, A
Chandrasekhar, V
Roesky, HW
Schmidt, HG
Noltemeyer, M
CHEMISCHE BERICHTE, 1996, 129 (04) : 391 - 395
[23] Manganese and cesium derivatives of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C.: Crystal structures of Li(THF)2.75(Et2O)0.25(μ-Cl)-MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and. (C6H6)3CsC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3
Eaborn, C
Hitchcock, PB
Smith, JD
Zhang, SB
Clegg, W
Izod, K
O'Shaughnessy, P
ORGANOMETALLICS, 2000, 19 (06) : 1190 - 1193
[24] [（Me3SiCH2）2Sn（OCOC6H4NO2-p）OSn（OH）(Me3SiCH2)2]2的合成和晶体结构
林森
王国永
付志飞
邓瑞红
何小立
方小牛
南昌大学学报(理科版), 2006, (03) : 236 - 238+243
[25] Reactions of co-ordinated ligands .63. Reaction of the eta(2)(4e)-donor alkyne complexes [Mo{eta(2)(4e)-R(1)C(2)R(2)}-{P(OMe)(3)}(2)(eta-C5H5)] (R(1)=R(2)=Ph or Me; R(1)=Me, R(2)=Ph) with the Grignard reagents MgR(3)(X) (R(3)=Me, Et, CH(2)Ph, CH2CH=CH2 or CH=CH2) and CH2(MgI)(2)
Brauers, G
Feher, FJ
Green, M
Hogg, JK
Orpen, AG
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (16): : 3387 - 3396
[26] PREPARATION AND PROPERTIES OF SOME ALLYLTIN CARBOXYLATES - R3SNOOCR'(R'=CH3, CH2CL), R2SN(OOCR')2 (R'=CH2CL, CHCL2) AND [R2SN(OOCR')]2O (R'=CH2CL, CHCL2, CCL3)
PERUZZO, V
PLAZZOGN.G
TAGLIAVI.G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 40 (01) : 121 - &
[27] SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF THE SILYLATED DIPHOSPHITES [(R1O)2PO]2SIR2R3 (R1 = ME, ET-R2, R3 = ME, PH, H, CH=CH2) - CRYSTAL-STRUCTURE OF [MNBR(CO)3(P(OME)2O)2SIME2]
SUM, V
PATEL, MT
KEE, TP
THORNTONPETT, M
POLYHEDRON, 1992, 11 (14) : 1743 - 1754
[28] Iodostannates with polymeric anions:: (Me3PhN)42∞[Sn3I10], [Me2HN-(CH2)2-NMe2H]21∞[Sn3I10], and [Me2HN-(CH2)2-NMe2H]2∞[Sn3I8]
Lode, C
Krautscheid, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (07): : 1454 - 1458
[29] Direct observation of (Me3ECH2)5Ta (E = C, Si) as the precursors to (Me3SiCH2)3Ta=CHEMe3 and (Me3SiCH2)2Ta(μ-CSiMe3)2Ta(CH2SiMe3 )2, kinetic and mechanistic studies of the formation of alkylidene and alkylidyne ligands
1600, ACS, Washington, DC, USA (117):
[30] Synthesis and Crystal Structure of （CH2）3（3,5-Me2Pz）2. [PhBr2Sn（CH2）SnBr2Ph].2HBr.H2O （Pz=pyrazole）
WANG Zhi-Hong TANG Liang-Fu② CHAI Jian-Fang WANG Ji-Tao (Department of Chemistry
结构化学, 2002, (03) : 273 - 276

← 1 2 3 4 5 →